2018
DOI: 10.1021/acsomega.8b00779
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Metallic Nanocrystal Ripening on Inorganic Surfaces

Abstract: In this paper, we demonstrate the formation of hybrid nanostructures consisting of two distinctive components mainly in a one-to-one ratio. Thermolysis of inorganic nanotubes (INT) and closed-cage, inorganic fullerene-like (IF) nanoparticles decorated with a dense coating of metallic nanoparticles (M = Au, Ag, Pd) results in migration of relatively small NPs or surface-enhanced diffusion of atoms or clusters, generating larger particles (ripening). AuNP growth on the surface of INTs has been captured in real t… Show more

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Cited by 3 publications
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“…The formation of closely packed Au nanoparticle (NP) arrays has a profound effect on the physical and electrical properties of Au NP‐based films. For example, recent studies have reported that alkane thiol treatment of tetraoctylammonium bromide (TB)‐stabilized Au NPs on inorganic nanotubes weakens the interfacial interaction between the Au NPs and inorganic surfaces, thereby increasing the mobility of Au NPs, which grow through Ostwald ripening . It was also reported that neighboring Ag NPs with an interparticle separation of less than 5 Å can be fused, forming strong metallic bonds .…”
mentioning
confidence: 99%
“…The formation of closely packed Au nanoparticle (NP) arrays has a profound effect on the physical and electrical properties of Au NP‐based films. For example, recent studies have reported that alkane thiol treatment of tetraoctylammonium bromide (TB)‐stabilized Au NPs on inorganic nanotubes weakens the interfacial interaction between the Au NPs and inorganic surfaces, thereby increasing the mobility of Au NPs, which grow through Ostwald ripening . It was also reported that neighboring Ag NPs with an interparticle separation of less than 5 Å can be fused, forming strong metallic bonds .…”
mentioning
confidence: 99%