Metal organic framework-integrated chitosan/poly(vinyl alcohol) (PVA) nanofibrous membrane hybrids from green process for selective CO2 capture and filtration

Jiamjirangkul, Phendaow; Inprasit, Thitirat; Intasanta, Varol; Pangon, Autchara

doi:10.1016/j.ces.2020.115650

Cited by 47 publications

(21 citation statements)

References 56 publications

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“…Also, Jiamjirangkul et al (2020) have studies on gas sorption suggested that the immersion of chitosan nanofibres in Cu-BTC (copper benzene-1,3,5-tricarboxylate) metal-organic frameworks. The chitosan nanofibres on (copper benzene-1,3,5-tricarboxylate) metal-organic frameworks presented great specific surface area ( 104.6 m 2 ∕g ), with uptake potential of CO 2 ∕N 2 above 14 times possesses an exceptional potential for uptake and filtration of CO 2 .…”

Section: Membranes Separationmentioning

confidence: 99%

Recent advances in carbon capture storage and utilisation technologies: a review

et al. 2020

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Human activities have led to a massive increase in $$\hbox {CO}_{2}$$ CO 2 emissions as a primary greenhouse gas that is contributing to climate change with higher than $$1\,^{\circ }\hbox {C}$$ 1 ∘ C global warming than that of the pre-industrial level. We evaluate the three major technologies that are utilised for carbon capture: pre-combustion, post-combustion and oxyfuel combustion. We review the advances in carbon capture, storage and utilisation. We compare carbon uptake technologies with techniques of carbon dioxide separation. Monoethanolamine is the most common carbon sorbent; yet it requires a high regeneration energy of 3.5 GJ per tonne of $$\hbox {CO}_{2}$$ CO 2 . Alternatively, recent advances in sorbent technology reveal novel solvents such as a modulated amine blend with lower regeneration energy of 2.17 GJ per tonne of $$\hbox {CO}_{2}$$ CO 2 . Graphene-type materials show $$\hbox {CO}_{2}$$ CO 2 adsorption capacity of 0.07 mol/g, which is 10 times higher than that of specific types of activated carbon, zeolites and metal–organic frameworks. $$\hbox {CO}_{2}$$ CO 2 geosequestration provides an efficient and long-term strategy for storing the captured $$\hbox {CO}_{2}$$ CO 2 in geological formations with a global storage capacity factor at a Gt-scale within operational timescales. Regarding the utilisation route, currently, the gross global utilisation of $$\hbox {CO}_{2}$$ CO 2 is lower than 200 million tonnes per year, which is roughly negligible compared with the extent of global anthropogenic $$\hbox {CO}_{2}$$ CO 2 emissions, which is higher than 32,000 million tonnes per year. Herein, we review different $$\hbox {CO}_{2}$$ CO 2 utilisation methods such as direct routes, i.e. beverage carbonation, food packaging and oil recovery, chemical industries and fuels. Moreover, we investigated additional $$\hbox {CO}_{2}$$ CO 2 utilisation for base-load power generation, seasonal energy storage, and district cooling and cryogenic direct air $$\hbox {CO}_{2}$$ CO 2 capture using geothermal energy. Through bibliometric mapping, we identified the research gap in the literature within this field which requires future investigations, for instance, designing new and stable ionic liquids, pore size and selectivity of metal–organic frameworks and enhancing the adsorption capacity of novel solvents. Moreover, areas such as techno-economic evaluation of novel solvents, process design and dynamic simulation require further effort as well as research and development before pilot- and commercial-scale trials.

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Section: Membranes Separationmentioning

confidence: 99%

Recent advances in carbon capture storage and utilisation technologies: a review

et al. 2020

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“…Metal‐organic frameworks (MOFs) have also been used in the functionalization of nanofibers by the LbL method. [ 171 ] For example, Jiamjirangkul and colleagues [ 172 ] used different approaches for the preparation of functionalized chitosan/PVA nanofibers (CNFs) with the MOF copper‐1,2,5‐benzenetricarboxylic‐acid (Cu‐BTC). The three approaches were: i) direct mixing of Cu‐BTC MOF with the polymeric solution and electrospinning; ii) in situ formation of Cu‐BTC MOF in CNFs; and iii) deposition of Cu‐BTC MOF on the surface of CNFs by the LbL method.…”

Section: Post‐modification Methods For Micro/nanofibermentioning

confidence: 99%

“…Furthermore, variations in (iii) deposition of Cu‐BTC precursors were also investigated, with the possibility of tailoring the morphology of CNFs according to the order of deposition of Cu‐BTC precursors, which presented a potential for gas separation and filtration. [ 172 ] Other studies reported the post‐functionalization of nanofibers by the LbL method with polyoxometalates (POMs), [ 173 ] GO, [ 174 ] MoS 2 nanosheets, [ 175 ] and transition metal carbides and carbonitrides (MXenes) [ 176 ] aiming at applications in catalysis, optical sensors, energy storage systems, and supercapacitors.…”

Section: Post‐modification Methods For Micro/nanofibermentioning

confidence: 99%

Tailoring the Surface Properties of Micro/Nanofibers Using 0D, 1D, 2D, and 3D Nanostructures: A Review on Post‐Modification Methods

Schneider

Facure

Chagas

et al. 2021

Adv Materials Inter

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Micro‐ and nanofibers produced by electrospinning and solution blow spinning (SBS) are highly suitable platforms for diverse applications due to their advantageous properties, including the high surface area to volume ratio, high porosity, and flexibility. To render them additional functionalities, distinct pre‐ or post‐modification processes have been proposed for modifying such micro‐ and nanofibers with 0D, 1D, 2D, and 3D nanostructures. The pre‐modification requires the addition of 0D–3D nanostructures (or their precursors) into the polymeric phase before the spinning process, which can demand laborious solubilization and requires changes in experimental spinning parameters, with impact on morphology, spinnability, and properties. Post‐modification methods, on the other hand, enable the fabrication of composite fibers without the need to optimize the spinning parameters, allowing a simple and efficient surface modification. Herein, recent advances on post‐modification methods of spun fibers, including wet chemistry, grafting, crosslinking, click chemistry, oxidations, hydrolysis and reduction strategies, dip‐coating, layer‐by‐layer, electro/air‐spray, atomic layer deposition, and plasma techniques aiming at the surface functionalization with 0D–3D nanostructures are surveyed. Recent results, trends, and challenges on the application of such surface‐modified fibers for environmental, industrial, and medical applications, including as adsorbent and filtering membranes, catalysts for pollutants degradation, and wearable sensors are examined.

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“…Furthermore, the resistance changes in the MOF-PAN hybrid fiber could sense the fast and slow breathing indicating the condition of the patient [ 73 ] Cu- 1,3,5-benzenetricarboxylic acid (BTC) MOF-based chitosan (CNF)/poly (vinyl alcohol) (PVA) electrospun nanofiber for selective CO 2 capture CNFs/BTC/Cu-3 which showed wider pore range of 0.7 to 1.1 nm. The CNF/Cu/BTC-3 also showed preferential adsorption of CO 2 to be 14 times more than N 2 at 298 K and 100 kPa [ 74 ] Antimicrobial fibers Silver nanoparticles (AgNPs) containing PVA nanofiber membranes were electrospun and grafted with 3,3′,4,4′-benzophenone tetracarboxylic acid (BPTA) which generate reactive oxygen species (OH and H 2 O 2 ) to impart antibacterial properties Tight-fitting masks with small fans performed better than masks without fans [ 75 ] AgNP containing PVDF nanofiber were electrospun for multifunctional applications by incorporating alumina Al 2 O 3 nanoparticles Membranes reduced particulates (> 99%) as well as a detoxifying model nerve agent (> 36%). The detoxifying and filtration properties improved with increasing Al 2 O 3 and were highest at 8% Al 2 O 3 [ 76 ] Electrospun chitosan/poly (vinyl alcohol) nanofiber membrane surface modified with SiO 2 and Ag nanoparticles Hydrophilic and antibacterial properties shown by membranes with addition of SiO 2 and Ag nanoparticles respectively.…”

Section: New Trends In Materials and Designs For Face Maskmentioning

confidence: 99%

“…They also found the order of deposition of MOF influenced pore size and CNFs/Cu/BTC with 3 times BTC deposition showed more uniform pore range (0.6 to 0.8 nm) as compared to CNFs/BTC/Cu-3 which showed wider pore range of 0.7 to 1.1 nm. The CNF/Cu/BTC-3 also showed preferential adsorption of CO 2 to be 14 times more than N 2 at 298 K and 100 kPa [ 74 ].…”

Section: New Trends In Materials and Designs For Face Maskmentioning

confidence: 99%

Electrospun nanofiber-based respiratory face masks—a review

Naragund

Panda

2022

emergent mater.

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The severe acute respiratory syndrome coronavirus (SARS-CoV-2) pandemic of 2019 forced widespread use of face coverings as a mandatory step towards reducing infection by the virus. The face mask acts as a barrier for transmission of infected aerosols among its user and surrounding people. This has propelled pace of research and development of face masks around the world. This short review is an effort to present advances in materials and designs used for face masks. Details available in scientific literature and company brochures have been accessed and the use of nanomaterials and designs for the new generation of face masks have been discussed. Special attention was given to the face masks based on electrospun nanofiber-based membrane materials due to their nano-sized pores, light weight, and high filtration efficiency; therefore, they are commercially viable and popular among various products available in the market. Incorporation of metal organic framework (MOFs) and graphene have opened avenues to more advanced/multi-functional, reusable, and high capacity adsorption filtration membranes. Rapid prototyping/3-dimensional (3-D) printing techniques have been applied to shorten the time of manufacture of face masks. This review is expected to be very helpful for engineers, scientists, and entrepreneurs working on development of novel face masks required in plenty during this pandemic period.

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Metal organic framework-integrated chitosan/poly(vinyl alcohol) (PVA) nanofibrous membrane hybrids from green process for selective CO2 capture and filtration

Cited by 47 publications

References 56 publications

Recent advances in carbon capture storage and utilisation technologies: a review

Recent advances in carbon capture storage and utilisation technologies: a review

Tailoring the Surface Properties of Micro/Nanofibers Using 0D, 1D, 2D, and 3D Nanostructures: A Review on Post‐Modification Methods

Electrospun nanofiber-based respiratory face masks—a review

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