MENTHYLSUBSTITUIERTE PHOSPHORVERBINDUNGEN V<sup>1,2</sup> R<sub>(P)</sub>-TERT.-BUTYL-1-MENTHYLTHIOPHOSPHORYLCHLORID KRISTALL- UND MOLEKÜLSTRUKTUR, MNDO-RECHNUNGEN UND NMR-DATEN

Boese, Roland; Hägele, Gerhard; Kückelhaus, Wolfgang; Tossing, G.

doi:10.1080/03086648508074264

Cited by 10 publications

(1 citation statement)

References 3 publications

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“…Der Betrag von c3(C=S) nimmt von R = Me zu rBu geringfügig ab, während für die Cycloalkylderivate kein einheitlicher Gang erkennbar ist. Die Zuordnung der aliphatischen C-Atome erfolgte nach Literaturangaben und durch Vergleich der Kopplungskonstanten [12,23] …”

Section: C-nmr-spektrenunclassified

Phosphinsubstituierte Chelatliganden, XXIII [1] Darstellung und NMR-Spektren von Alkyl-arylphosphinothioformamiden, R(Ph)PC(S)NHMe / Phosphine-Substituted Chelate Ligands, XXIII [1] Synthesis and NMR Spectra of Alkyl-arylphosphinothioformamides, R(Ph)PC(S)NHMe

Kunze

Tittmann

1987

Zeitschrift Für Naturforschung B

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Abstract A series of alkyl-arylsubstituted N-methyl phosphinothioformamides, R(Ph)PC(S)NHMe (2 a-g), with varying bulkiness of the alkyl rest was synthesized from the racemic secondary phosphines 1a-g and methyl isothiocyanate. 1H and 13C NMR spectra of 2a−g reveal signal sets of diastereotopic nuclei due to the asymmetry of the molecule. The chemical shift and coupling constants were confirmed by simulation in case of 2b, c. The vicinal 31P−13C couplings of the menthyl and neomenthyl compounds 2f, g show an "anti-Karplus" behaviour (3J(gauche) > 3J(trans)) and allow the conformational assignment of the alicyclic group. The 31P chemical shifts of 2a−d give a linear correlation with the cone angle of the alkyl substituents quoted from literature.

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Section: C-nmr-spektrenunclassified

Phosphinsubstituierte Chelatliganden, XXIII [1] Darstellung und NMR-Spektren von Alkyl-arylphosphinothioformamiden, R(Ph)PC(S)NHMe / Phosphine-Substituted Chelate Ligands, XXIII [1] Synthesis and NMR Spectra of Alkyl-arylphosphinothioformamides, R(Ph)PC(S)NHMe

Kunze

Tittmann

1987

Zeitschrift Für Naturforschung B

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The Synthesis and Reactions of Thio‐ and Seleno‐Phosphonic and ‐Phosphinic Acids

Edmundson¹

2009

Patai's Chemistry of Functional Groups

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Introduction The Synthesis of Monothio‐ and Monoseleno‐Phosphonic and ‐Phosphinic Acids and their Derivatives Interconversions of the Monothio(or Seleno) ‐Phosphonic and ‐Phosphinic Acids and Their Derivatives Syntheses and Reactions of Di‐ and Tri‐Thio(Seleno)‐Phosphonic Acids and Dithio(Seleno)Phosphinic Acids

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ChemInform Abstract: Menthy1‐Substituted Phosphorus Compounds. Part 5. R_(P)tert‐Butyl‐1‐menthylthiophosphorylchloride.

Boese¹,

Haegele²,

Kueckelhaus³

et al. 1986

Chemischer Informationsdienst

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MENTHYLSUBSTITUIERTE PHOSPHORVERBINDUNGEN V^1,2 R_(P)-TERT.-BUTYL-1-MENTHYLTHIOPHOSPHORYLCHLORID KRISTALL- UND MOLEKÜLSTRUKTUR, MNDO-RECHNUNGEN UND NMR-DATEN

Cited by 10 publications

References 3 publications

Phosphinsubstituierte Chelatliganden, XXIII [1] Darstellung und NMR-Spektren von Alkyl-arylphosphinothioformamiden, R(Ph)PC(S)NHMe / Phosphine-Substituted Chelate Ligands, XXIII [1] Synthesis and NMR Spectra of Alkyl-arylphosphinothioformamides, R(Ph)PC(S)NHMe

Phosphinsubstituierte Chelatliganden, XXIII [1] Darstellung und NMR-Spektren von Alkyl-arylphosphinothioformamiden, R(Ph)PC(S)NHMe / Phosphine-Substituted Chelate Ligands, XXIII [1] Synthesis and NMR Spectra of Alkyl-arylphosphinothioformamides, R(Ph)PC(S)NHMe

The Synthesis and Reactions of Thio‐ and Seleno‐Phosphonic and ‐Phosphinic Acids

ChemInform Abstract: Menthy1‐Substituted Phosphorus Compounds. Part 5. R_(P)tert‐Butyl‐1‐menthylthiophosphorylchloride.

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MENTHYLSUBSTITUIERTE PHOSPHORVERBINDUNGEN V1,2 R(P)-TERT.-BUTYL-1-MENTHYLTHIOPHOSPHORYLCHLORID KRISTALL- UND MOLEKÜLSTRUKTUR, MNDO-RECHNUNGEN UND NMR-DATEN

Cited by 10 publications

References 3 publications

Phosphinsubstituierte Chelatliganden, XXIII [1] Darstellung und NMR-Spektren von Alkyl-arylphosphinothioformamiden, R(Ph)PC(S)NHMe / Phosphine-Substituted Chelate Ligands, XXIII [1] Synthesis and NMR Spectra of Alkyl-arylphosphinothioformamides, R(Ph)PC(S)NHMe

Phosphinsubstituierte Chelatliganden, XXIII [1] Darstellung und NMR-Spektren von Alkyl-arylphosphinothioformamiden, R(Ph)PC(S)NHMe / Phosphine-Substituted Chelate Ligands, XXIII [1] Synthesis and NMR Spectra of Alkyl-arylphosphinothioformamides, R(Ph)PC(S)NHMe

The Synthesis and Reactions of Thio‐ and Seleno‐Phosphonic and ‐Phosphinic Acids

ChemInform Abstract: Menthy1‐Substituted Phosphorus Compounds. Part 5. R(P)tert‐Butyl‐1‐menthylthiophosphorylchloride.

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MENTHYLSUBSTITUIERTE PHOSPHORVERBINDUNGEN V^1,2 R_(P)-TERT.-BUTYL-1-MENTHYLTHIOPHOSPHORYLCHLORID KRISTALL- UND MOLEKÜLSTRUKTUR, MNDO-RECHNUNGEN UND NMR-DATEN

ChemInform Abstract: Menthy1‐Substituted Phosphorus Compounds. Part 5. R_(P)tert‐Butyl‐1‐menthylthiophosphorylchloride.