Lithium insertion in layered materials as battery cathodes

Samaras, I.; Saikh, S.I.; Julien, C.; Bałkanski, M.

doi:10.1016/0921-5107(89)90203-1

Cited by 38 publications

(11 citation statements)

References 17 publications

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“…Copyright 1986 Kluwer Academic Press coordination that changes the octahedral one (TP ! Oh transition) [26][27][28]. The structure modification is accompanied by an increase of the M-X band ionicity in agreement with the respective stability of the new atomic arrangement, the Coulomb repulsion between partially charged ligands favoring the octahedral form.…”

Section: Lithium Intercalation In 2h-mossupporting

confidence: 56%

“…4.12) [31]. This superlattice formation was also observed in the incremental capacity dQ/dV obtained from electrochemical measurements [28] and in the Raman scattering spectra of Li 0.3 MoS 2 [32,33]. However, we do expect that the lithiation process is accompanied by the raising of the Fermi level due to the charge transfer from Li intercalation.…”

Section: Lithium Intercalation In 2h-mosmentioning

confidence: 54%

See 1 more Smart Citation

Reliability of the Rigid-Band Model in Lithium Intercalation Compounds

Julien¹,

Mauger²,

Vijh

et al. 2016

Lithium Batteries

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Section: Lithium Intercalation In 2h-mossupporting

confidence: 56%

Section: Lithium Intercalation In 2h-mosmentioning

confidence: 54%

Reliability of the Rigid-Band Model in Lithium Intercalation Compounds

Julien¹,

Mauger²,

Vijh

et al. 2016

Lithium Batteries

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“…[ 5,6 ] Intercalation chemistry in layered compounds, where the van der Waals (vdW) gap of the host compound is filled with guest (intercalant) atoms [ 7 ] or molecules, [ 8 ] is a cornerstone in many processes and forms the basis of modern energy storage devices. [ 9,10 ] In some cases, the intercalation process is designed to modify the properties of the host material, [ 11 ] whereas in other cases, intercalation produces a continuous 2D material of interest, that would be hard to realize without the template of the confining environment of the vdW gap. For example, 2D gallium and indium that are grown by atomic intercalation at the interface of SiC and graphene, show potential for superconducting devices, topological phenomena, and advanced optoelectronic properties.…”

Section: Introductionmentioning

confidence: 99%

Enhancing Light–Matter Interactions in MoS₂ by Copper Intercalation

et al. 2021

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The intercalation of layered compounds opens up a vast space of new host–guest hybrids, providing new routes for tuning the properties of materials. Here, it is shown that uniform and continuous layers of copper can be intercalated within the van der Waals gap of bulk MoS2 resulting in a unique Cu–MoS2 hybrid. The new Cu–MoS2 hybrid, which remains semiconducting, possesses a unique plasmon resonance at an energy of ≈1eV, giving rise to enhanced optoelectronic activity. Compared with high‐performance MoS2 photodetectors, copper‐enhanced devices are superior in their spectral response, which extends into the infrared, and also in their total responsivity, which exceeds 104 A W−1. The Cu–MoS2 hybrids hold promise for supplanting current night‐vision technology with compact, advanced multicolor night vision.

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“…Furthermore, the weak van der Waals force between MoS 2 layers allows Li + ions to diffuse without a significant increase in volume expansion. These properties make MoS 2 an ideal electrode material for advanced LIBs [54, 55]. …”

Section: Moo2 and Mos2 As Promising Electrode Materials For Libsmentioning

confidence: 99%

Synthesis of MoS₂and MoO₂for their applications in H₂generation and lithium ion batteries: a review

Zhao

Zhang

Yang

et al. 2013

Science and Technology of Advanced Materials

120

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Scientists increasingly witness the applications of MoS2 and MoO2 in the field of energy conversion and energy storage. On the one hand, MoS2 and MoO2 have been widely utilized as promising catalysts for electrocatalytic or photocatalytic hydrogen evolution in aqueous solution. On the other hand, MoS2 and MoO2 have also been verified as efficient electrode material for lithium ion batteries. In this review, the synthesis, structure and properties of MoS2 and MoO2 are briefly summarized according to their applications for H2 generation and lithium ion batteries. Firstly, we overview the recent advancements in the morphology control of MoS2 and MoO2 and their applications as electrocatalysts for hydrogen evolution reactions. Secondly, we focus on the photo-induced water splitting for H2 generation, in which MoS2 acts as an important co-catalyst when combined with other semiconductor catalysts. The newly reported research results of the significant functions of MoS2 nanocomposites in photo-induced water splitting are presented. Thirdly, we introduce the advantages of MoS2 and MoO2 for their enhanced cyclic performance and high capacity as electrode materials of lithium ion batteries. Recent key achievements in MoS2- and MoO2-based lithium ion batteries are highlighted. Finally, we discuss the future scope and the important challenges emerging from these fascinating materials.

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Lithium insertion in layered materials as battery cathodes

Cited by 38 publications

References 17 publications

Reliability of the Rigid-Band Model in Lithium Intercalation Compounds

Reliability of the Rigid-Band Model in Lithium Intercalation Compounds

Enhancing Light–Matter Interactions in MoS₂ by Copper Intercalation

Synthesis of MoS₂and MoO₂for their applications in H₂generation and lithium ion batteries: a review

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Lithium insertion in layered materials as battery cathodes

Cited by 38 publications

References 17 publications

Reliability of the Rigid-Band Model in Lithium Intercalation Compounds

Reliability of the Rigid-Band Model in Lithium Intercalation Compounds

Enhancing Light–Matter Interactions in MoS2 by Copper Intercalation

Synthesis of MoS2and MoO2for their applications in H2generation and lithium ion batteries: a review

Contact Info

Product

Resources

About

Enhancing Light–Matter Interactions in MoS₂ by Copper Intercalation

Synthesis of MoS₂and MoO₂for their applications in H₂generation and lithium ion batteries: a review