Conductivity behavior of the Bi12TiO20 single crystal was investigated by the electric modulus spectroscopy, which was carried out in the frequency range from 5 Hz to 13 MHz and at temperatures higher than 400 °C. The resistance curve exhibits a set of properties correlated to a negative temperature coefficient thermistor. In the temperature range investigated, the characteristic parameter (β) of the thermistor is equal to 4834 °C. Temperature coefficients of the resistance (α) were derived being equal to −3.02×10−2°C−1 at 400 °C and equal to −9.86×10−3°C−1 at 700 °C. The nature of the electric relaxation phenomenon and magnitude dc conductivity are approached.