Latest trends in the large-scale production of MOFs in accordance with the principles of green chemistry

Pobłocki, Kacper; Drzeżdżon, Joanna; Gawdzik, Barbara; Jacewicz, Dagmara

doi:10.1039/d2gc03264c

Cited by 26 publications

(14 citation statements)

References 182 publications

(366 reference statements)

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“…44 Although H 2 O is a much greener solvent in theory, 45 DMF possesses a stronger deprotonation ability that facilitates the coordination reactions of metal ions and organic ligands and then regulates the catalytic activities of MOCCs. 46 Hence, DMF was widely used as a solvent to synthesize various MOCCs in the previous reports. [47][48][49] Based on these facts, the synthesis of Zr-GC-SO 3 H-X and Zr-GHTC in this work was also conducted in DMF.…”

Section: Methodsmentioning

confidence: 99%

Highly effective synthesis of biomass-derived furanic diethers over a sulfonated zirconium–carbon coordination catalyst in alcohol systems

Shen

Zheng

et al. 2023

Green Chem.

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Section: Methodsmentioning

confidence: 99%

Highly effective synthesis of biomass-derived furanic diethers over a sulfonated zirconium–carbon coordination catalyst in alcohol systems

Shen

Zheng

et al. 2023

Green Chem.

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“…Several solvent free synthesis methods such as mechanochemical, microwave, ultrasound, etc., are expected to achieve large-scale production. 197 Loading effective MOFs on low-cost substrates is also of great potential to reduce production costs. Continuous improvement could focus on preparing multi-functional MOFs on a large scale.…”

Section: Summary and Prospectsmentioning

confidence: 99%

Functional metal–organic frameworks as adsorbents used for water decontamination: design strategies and applications

et al. 2023

J. Mater. Chem. A

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“…have been successfully grown onto various substrates including Au interdigitated electrodes (IDEs) and α-Al 2 O 3 substrates. 88 The direct growth approach offers obvious advantages for the MOF film fabrication. For instance, it allows for the precise control of the film thickness, morphology, and composition.…”

Section: ■ Integration Of Mofs Onto Sensing Devicesmentioning

confidence: 99%

Metal–Organic Framework Coated Devices for Gas Sensing

Peng

Zhang

et al. 2023

ACS Sens.

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The demand for monitoring chemical and physical information surrounding, air quality, and disease diagnosis has propelled the development of devices for gas sensing that are capable of translating external stimuli into detectable signals. Metal−organic frameworks (MOFs), possessing particular physiochemical properties with designability in topology, specific surface area, pore size and/or geometry, potential functionalization, and host−guest interactions, reveal excellent development promises for manufacturing a variety of MOF-coated sensing devices for multitudinous applications including gas sensing. The past years have witnessed tremendous progress on the preparation of MOF-coated gas sensors with superior sensing performance, especially high sensitivity and selectivity. Although limited reviews have summarized different transduction mechanisms and applications of MOF-coated sensors, reviews summarizing the latest progress of MOF-coated devices under different working principles would be a good complement. Herein, we summarize the latest advances of several classes of MOF-based devices for gas sensing, i.e., chemiresistive sensors, capacitors, field-effect transistors (FETs) or Kelvin probes (KPs), electrochemical, and quartz crystal microbalance (QCM)-based sensors. The surface chemistry and structural characteristics were carefully associated with the sensing behaviors of relevant MOF-coated sensors. Finally, challenges and future prospects for long-term development and potentially practical application of MOF-coated sensing devices are pointed out.

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Latest trends in the large-scale production of MOFs in accordance with the principles of green chemistry

Abstract: More and more research centers are focusing on patents that allow the production of metal-organic frameworks (MOFs) on a large scale. MOFs, due to their porous structure, have been used...

Cited by 26 publications

References 182 publications

Highly effective synthesis of biomass-derived furanic diethers over a sulfonated zirconium–carbon coordination catalyst in alcohol systems

Highly effective synthesis of biomass-derived furanic diethers over a sulfonated zirconium–carbon coordination catalyst in alcohol systems

Functional metal–organic frameworks as adsorbents used for water decontamination: design strategies and applications

Metal–Organic Framework Coated Devices for Gas Sensing

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