“…No significant difference is observed among the spectra of these samples, suggesting similar surface functional groups regardless of the biochar-to-KOH ratio. The presence of such functional groups was also reported by Barkauskas et al [40] for commercial granulated activated carbon.…”
Synthesis of activated carbon from waste biomass is of current interest towards sustainability. The properties of biomass-derived activated carbon largely depend on the carbonization process. This study reports the preparation of mesoporous activated carbon with extremely high surface area from hemp bast fiber using hydrothermal processing. Hot water processing (390-500 • C) followed by activation using KOH and NaOH was investigated at different mass ratios. The described approach was found to enhance the mesoporosity (centered at 3.0 to 4.5 nm) of the hemp-derived activated carbon (HAC) from activation [confirmed by BJH (Barrett-Joyner-Halenda) pore size distribution and TEM (transmission electron microscopy) imaging]. BET (Brunauer-Emmett-Teller) results showed that the product has an extremely high surface area (2425 m 2 /g) while the surface functional groups (-OH, -COOH, C=C/C-C) were confirmed by FTIR (Fourier transform infrared spectroscopy) and further quantified by XPS (X-ray photoelectron spectroscopy). Increasing KOH concentration was found to enhance the surface area with a maximum biochar-to-KOH (g/g) ratio of 1:3. The crystallite domain size of HAC was determined using Raman spectroscopy of different wavelengths. The procedure described in this study is an environmentally friendly scalable route for the mass production of activated carbon using hemp fiber.
“…No significant difference is observed among the spectra of these samples, suggesting similar surface functional groups regardless of the biochar-to-KOH ratio. The presence of such functional groups was also reported by Barkauskas et al [40] for commercial granulated activated carbon.…”
Synthesis of activated carbon from waste biomass is of current interest towards sustainability. The properties of biomass-derived activated carbon largely depend on the carbonization process. This study reports the preparation of mesoporous activated carbon with extremely high surface area from hemp bast fiber using hydrothermal processing. Hot water processing (390-500 • C) followed by activation using KOH and NaOH was investigated at different mass ratios. The described approach was found to enhance the mesoporosity (centered at 3.0 to 4.5 nm) of the hemp-derived activated carbon (HAC) from activation [confirmed by BJH (Barrett-Joyner-Halenda) pore size distribution and TEM (transmission electron microscopy) imaging]. BET (Brunauer-Emmett-Teller) results showed that the product has an extremely high surface area (2425 m 2 /g) while the surface functional groups (-OH, -COOH, C=C/C-C) were confirmed by FTIR (Fourier transform infrared spectroscopy) and further quantified by XPS (X-ray photoelectron spectroscopy). Increasing KOH concentration was found to enhance the surface area with a maximum biochar-to-KOH (g/g) ratio of 1:3. The crystallite domain size of HAC was determined using Raman spectroscopy of different wavelengths. The procedure described in this study is an environmentally friendly scalable route for the mass production of activated carbon using hemp fiber.
“…Surfacef unctionalization is one of the effective methods used Figure 6. [65] Franckowiak et al explained that the presenceo fs urfacef unctional groups could modify the electronic properties (electron-donor or -acceptor properties) of carbon materials, which, in turn, could affect the EDLC chargingm echanism andi nduce pseudocapacitance faradaic reactions. a) Plot of specific capacitance normalized by BET SSA for the carbons in this studyand in two other studies with identical electrolytes.…”
4357Reviews Scheme1.Classificationo fS Cs based on the charge-storage mechanism and type of active materials used in bothelectrodes. CDC = carbide-derived carbon, CNT = carbon nanotube.
“…The increase and decreases in the spectrum peaks shows how the treatment conditions affect the structure of material [22]. The amounts of functional groups can be determined by potentiometric titration which positively correlates with the intensity of the peaks of hydrophilic functional groups in the FTIR spectra [23]. Therefore, if the same procedure is used in sample preparation for IR spectroscopy including the same amount and homogeneity of the sample dispersed in the KBr pellet method, the intensity of peaks can be used for quantitative comparison of functional groups.…”
Section: Characterization Of Activated Carbon Supportsmentioning
confidence: 99%
“…The peaks of these heteroatom containing groups (C-X, X: O, N, S and Cl) overlap with each other and could not be easily identified. Therefore, the concept of conventional functional groups is often used to characterize the surfaces of active carbon [23].…”
Section: Characterization Of Activated Carbon Supportsmentioning
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