Introduction of Fullerene as a New Carrier in Electromembrane Extraction for the Determination of Ibuprofen and Sodium Diclofenac as Model Acidic Drugs in Real Urine Samples

Atarodi, Atefe; Chamsaz, Mahmoud; Moghaddam, Ali Zeraatkar; Tabani, Hadi

doi:10.1007/s10337-017-3295-1

Cited by 17 publications

(4 citation statements)

References 49 publications

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“…These solvents have relatively high polarity (π*), strong hydrogen-bond acidity (α), and basicity (β) which makes them suitable for the extraction of acidic compounds. [34][35][36] Among the tested solvents, 1-octanol, due to its suitable viscosity and low vapor pressure, provided a stable membrane for the EME of ETX. [37] 3.1.…”

Section: Supported Liquid Membrane (Slm) Compositionmentioning

confidence: 99%

Sensitive determination of ethosuximide in human fluids by electromembrane extraction coupled with high performance liquid chromatography ultraviolet spectroscopy

Nabizadeh

Mohammadi

Dolatabadi

et al. 2022

J Chinese Chemical Soc

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Ethosuximide (ETX) is a common antiepileptic drug in the first line of absence epilepsy. In this study, for the first time, an economical and efficient electro‐membrane (EME) method for determination of ETX in a complex biological matrix using HPLC‐UV has been developed. Factors affecting conventional EME were evaluated. 1‐Octanol was immobilized in a polypropylene membrane and a voltage of 35 V was applied between two platinum electrodes for 15 min. The pH of acceptor and donor phases for ionization of ETX was adjusted to 13 and 11, respectively. Under optimal microextraction conditions, the enrichment factor was 21.02 and the linear range of ETX was 0.25 to 8.00 μg/mL with an acceptable R2 ≥ 0.9986. Inter‐day and intra‐day precision and accuracy of the suggested method were calculated with RSD < 9.5% and relative error <7.0%, respectively. The mean relative recovery of ETX in the human saliva and plasma samples was 81.68% and 74.47, respectively; while limit of detection and quantification concentrations were 0.08 and 0.25 μg/mL, respectively. Furthermore, to evaluate the application of the method, plasma and saliva samples of volunteers administering a single dose of ETX were analyzed successfully by EME‐HPLC‐UV method.

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Section: Supported Liquid Membrane (Slm) Compositionmentioning

confidence: 99%

Sensitive determination of ethosuximide in human fluids by electromembrane extraction coupled with high performance liquid chromatography ultraviolet spectroscopy

Nabizadeh

Mohammadi

Dolatabadi

et al. 2022

J Chinese Chemical Soc

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“…At the same time Atarodi et al (2017) developed EME combined with high-performance liquid chromatography (HPLC) coupled with ultraviolet (UV) detection for analysis of ibuprofen and sodium diclofenac in urine samples (Atarodi et al, 2017). Also, Akkaya (2017) investigated a combination of slotted quartz tube attached to flame atomic absorption spectrometry and stearic acid-coated magnetite nanoparticle-based SPME for the determination of ultratrace amounts of cadmium in urine samples.…”

Section: Urinementioning

confidence: 99%

Recent applications of microextraction sample preparation techniques in biological samples analysis

Daryanavard

Zolfaghari

Abdel-Rehim

et al. 2021

Biomedical Chromatography

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Analysis of biological samples is affected by interfering substances with chemical properties similar to those of the target analytes, such as drugs. Biological samples such as whole blood, plasma, serum, urine and saliva must be properly processed for separation, purification, enrichment and chemical modification to meet the requirements of the analytical instruments. This causes the sample preparation stage to be of undeniable importance in the analysis of such samples through methods such as microextraction techniques. The scope of this review will cover a comprehensive summary of available literature data on microextraction techniques playing a key role for analytical purposes, methods of their implementation in common biological samples, and finally, the most recent examples of application of microextraction techniques in preconcentration of analytes from urine, blood and saliva samples. The objectives and merits of each microextration technique are carefully described in detail with respect to the nature of the biological samples. This review presents the most recent and innovative work published on microextraction application in common biological samples, mostly focused on original studies reported from 2017 to date. The main sections of this review comprise an introduction to the microextraction techniques supported by recent application studies involving quantitative and qualitative results and summaries of the most significant, recently published applications of microextracion methods in biological samples. This article considers recent applications of several microextraction techniques in the field of sample preparation for biological samples including urine, blood and saliva, with consideration for extraction techniques, sample preparation and instrumental detection systems.

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“…EME refers to the receiving solution of charged targets by the supported liquid membrane in electric field. Recently, many novel membrane materials have been developed to improve extraction performance of EME, including combined materials, − polymer inclusion membranes, , and gel membranes. , Particularly, to save the time for dried blood tests, Breadmore’s group developed an in-transit EME method to pretreat sample on the way to the laboratory, which showing potential in point-of-care tests …”

Section: Energy Exchange Accelerationmentioning

confidence: 99%

Recent Progress in Fast Sample Preparation Techniques

et al. 2019

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Introduction of Fullerene as a New Carrier in Electromembrane Extraction for the Determination of Ibuprofen and Sodium Diclofenac as Model Acidic Drugs in Real Urine Samples

Cited by 17 publications

References 49 publications

Sensitive determination of ethosuximide in human fluids by electromembrane extraction coupled with high performance liquid chromatography ultraviolet spectroscopy

Sensitive determination of ethosuximide in human fluids by electromembrane extraction coupled with high performance liquid chromatography ultraviolet spectroscopy

Recent applications of microextraction sample preparation techniques in biological samples analysis

Recent Progress in Fast Sample Preparation Techniques

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