Innentitelbild: Controlled Reducibility of a Metal–Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption (Angew. Chem. 34/2010)

Green Microwave Synthesis of MIL‐100(Al, Cr, Fe) Nanoparticles for Thin‐Film Elaboration

“…5 and 8.5 Å. In addition, the presence of accessible unsaturated Lewis acid metal sites (coordinatively unsaturated metal sites, CUS) allows the coordination of different species, [39][40][41] which makes them interesting candidates for catalysis, [42,43] separation, [35,41,[44][45][46] and biomedical applications. In addition, the presence of accessible unsaturated Lewis acid metal sites (coordinatively unsaturated metal sites, CUS) allows the coordination of different species, [39][40][41] which makes them interesting candidates for catalysis, [42,43] separation, [35,41,[44][45][46] and biomedical applications.…”

Carbon monoxide separation: past, present and future

“…The adsorption of CO on MIL-100(Fe) was studied by Yoon et al 128 The oxidation states of iron and the amount of open metal sites were quantified using in situ IR spectroscopic analysis under CO atmosphere. At room temperature, CO molecules interact weakly with the Fe 3+ sites in the network as confirmed by a weak band at 2190 cm À1 and an adsorption enthalpy of À39 to À28 kJ mol À1 .…”

Electrostatic assembly of gold nanoparticle and metal–organic framework nanoparticles attenuates amyloid β aggregate-mediated neurotoxicity

“…Thus, the proper surface coating is an important aspect for the bio-application of MIL-101. 19,20 In this study, we used PEG-NH 2 to improve the biocompatibility of MIL-101 (PEG@MIL-101). Subsequently, our result indicated that PEG@MIL-101 could interact with the Ab monomer.…”