Green Microwave Synthesis of MIL‐100(Al, Cr, Fe) Nanoparticles for Thin‐Film Elaboration

Abstract

SSCI-VIDE+CDFA+ADMInternational audienc

Heparin‐Engineered Mesoporous Iron Metal‐Organic Framework Nanoparticles: Toward Stealth Drug Nanocarriers

“…NPs of the mesoporous iron(III) trimesate MIL-100(Fe) have been selected and synthesized via a biologically and environmentally favorable method, [ 23,24 ] due to their lack of in vivo toxicity, [ 25 ] as well as for their ability to encapsulate and release biologically relevant cargoes and their interesting theranostics properties. [ 17,19,26 ] In essence, the ideal nanoMOFs coating should: (i) be selectively attached on the external surface while avoiding intrusion inside the porous; (ii) not interact with the encapsulated moieties; (iii) display suitable stability under physiological conditions; and fi nally (iv) enhance nanoMOF performances for bioapplications, such as improvement of their colloidal stability or modulate their biodistribution.…”

Iron‐Based Metal‐Organic Frameworks (MOF) as Photocatalysts for Radical and Cationic Polymerizations under Near UV and Visible LEDs (385–405 nm)

“…The investigated MOFs and other chemical compounds are shown in Table and Scheme . MIL100 (either as micro‐ or nano‐metric particles‐MIL100nano), MIL127, MIL88A, MIL88B, and MIL53 materials, presented in detail in the references, were hydro/solvothermally synthesized, as previously reported . Diphenyliodonium hexafluorophosphate (Iod), N ‐vinylcarbazole (NVK), and the other reagents and solvents were purchased from Sigma‐Aldrich or Alfa Aesar for the highest purity available and used as received without further purification.…”

Postsynthesis‐Treated Iron‐Based Metal–Organic Frameworks as Selective Catalysts for the Sustainable Synthesis of Nitriles

“…[45,46] Moreover,d uring the synthesis of MOFs, another important parametert hat can influence their catalytic activity is the degree of purification of the MOF. [47,48] Recently,S eo et al [49] developed ap urification methodt hat combines solvent extraction (hot water and ethanol) and at reatment with aqueous NH 4 Fs olution at 70 8C. [47,48] Recently,S eo et al [49] developed ap urification methodt hat combines solvent extraction (hot water and ethanol) and at reatment with aqueous NH 4 Fs olution at 70 8C.…”

“…The sample of MIL-100 (Fe) was synthesized by am icrowave-assisted hydrothermal method as reported by Mµrquez et al [47] Typically,i ron(III) chloride hexahydrate (2.43 g, 9mmol) was dissolved in distilled water (30 mL) with stirring. The sample of MIL-100 (Fe) was synthesized by am icrowave-assisted hydrothermal method as reported by Mµrquez et al [47] Typically,i ron(III) chloride hexahydrate (2.43 g, 9mmol) was dissolved in distilled water (30 mL) with stirring.…”

“…After centrifugation at 10 500 rpm for 25 min, the orange solid (2.5 g) was washed first with distilled water (30 mL) at 70 8Cu nder stirring for 3hand then with ethanol at 65 8Cf or 3h.T he catalyst was dried in the oven at 100 8Co vernight and was then treated with as olution of NH 4 F (38 mm,2 0mL) at 70 8Cf or 3h.A fter cooling, the precipitate was collected by filtration and washed with hot water (60 8C, 5 200 mL) to remove traces of NH 4 F. [47] UiO-66 (Zr) was synthesized following ap rocedure described in the literature. After centrifugation at 10 500 rpm for 25 min, the orange solid (2.5 g) was washed first with distilled water (30 mL) at 70 8Cu nder stirring for 3hand then with ethanol at 65 8Cf or 3h.T he catalyst was dried in the oven at 100 8Co vernight and was then treated with as olution of NH 4 F (38 mm,2 0mL) at 70 8Cf or 3h.A fter cooling, the precipitate was collected by filtration and washed with hot water (60 8C, 5 200 mL) to remove traces of NH 4 F. [47] UiO-66 (Zr) was synthesized following ap rocedure described in the literature.…”