“…22 It has been previously reported that group I metals such as Ag and Cu are fast-diffusing impurities in II-VI compounds, by this token, Ag + ions can occupy the Zn 2+ lattice sites in ZnS and can act as effective luminescent centers which are known to form the so-called blue centers. 23,24 Besides the contribution to optical property, the substitutional doping of Ag + in the ZnS NRs by replacing Zn 2+ could also account for the observed p-type characteristic of the NRs which will be discussed later on.…”