“…To figure out the corrosion mechanism of metal/coating system and quickly evaluate its corrosion resistance, accelerated test methods, such as immersion test, [ 2,11–13 ] salt spray test, [ 1,2,14–16 ] and CASS spectrum test [ 17 ] have been widely used, and the evaluation methods can be visual, [1, 13,15 ] electrochemical, [ 2,3,11,14,16 ] mechanical, [ 3,14 ] and so on. Among them, the traditional electrochemical impedance spectroscopy (EIS) technology has become one of the most effective tools to study the degradation process of the metal/coating system, [ 2,16 ] but its disadvantage is that the measured electrochemical signal is the average information of the measured area, and cannot provide the information of local microscopic corrosion reaction.…”