Influence of 4-tert-butylpyridine/guanidinium thiocyanate co-additives on band edge shift and recombination of dye-sensitized solar cells: experimental and theoretical aspects
“…In order to further study the relationship between dye structures and device performances, the charge density (d n ) at open circuit and the electron lifetime (s) as a function of charge density were measured by controlled intensity modulated photovoltage spectroscopy (IMVS). [38][39][40] The results indicate that the introduction of 10-phenyl-10H-phenothiazine and truxene onto DTP spacers of JW1 and JW2 is benet to enhance the photovoltaic performances of DSSCs by more efficiently reduce electron recombination, as compared to the introduction of 4hexyloxyphenyl onto DTP spacers of JW3. As shown in Fig.…”
Section: Photovoltaic Performances Of Dsscsmentioning
“…In order to further study the relationship between dye structures and device performances, the charge density (d n ) at open circuit and the electron lifetime (s) as a function of charge density were measured by controlled intensity modulated photovoltage spectroscopy (IMVS). [38][39][40] The results indicate that the introduction of 10-phenyl-10H-phenothiazine and truxene onto DTP spacers of JW1 and JW2 is benet to enhance the photovoltaic performances of DSSCs by more efficiently reduce electron recombination, as compared to the introduction of 4hexyloxyphenyl onto DTP spacers of JW3. As shown in Fig.…”
Section: Photovoltaic Performances Of Dsscsmentioning
“…Aiming to meet the commercialization needs, various thin film device technologies have been developed to reduce the material and manufacture costs of solar cells . Among them, dye‐sensitized solar cell (DSC) technology is a promising candidate possessing benefits such as abundance of available materials, relatively low material and manufacture costs, various outdoor/indoor applications, as well as an industrial production desired low‐tech construction process . In the middle of a DSC device, dye molecules attach on mesoporous semiconductor network, normally TiO 2 .…”
The development of a suitable material with both effective light scattering and high surface adhesion properties that would allow a low‐temperature fabrication of a mechanically stable light trapping layer is critical for today's flexible plastic dye‐sensitized solar cells (DSCs) to reach comparable high power conversion efficiency (PEC) towards commercialization. In the present work, submicron‐sized titania particles of intensive surface roughness were strategically synthesized using a combined sol–gel and thermolysis approach. When used as a light‐trapping layer in flexible DSCs, the ideal strong light scattering ability of such materials enabled significant enhancement of light harvesting and thus greatly contributed to the photocurrent performances. This led to a nearly 30 % PEC improvement when compared to the flexible DSCs using nanoparticle‐based photoanodes of a similar film thickness.
“…[33][34][35] The organic additives 43,44 utilized such as 4-tert-butyl pyridine (TBP) and guanidinium thiocyanate (GuSCN) can inuence the downward displacement of TiO 2 to be continued with its negative potential shi. [36][37][38][39][40]47 Moreover, they act as a replacement for excellent metal oxide nano-llers. Organic additives preferably play a well-expressed role in many energy applications such as OLEDs 41 and DSSCs.…”
A unique gel polymer electrolyte was prepared using PVDF and PEG–PPG–PEG block copolymer with I−/I3− for DSSC application. This is a cost-effective method used for the synthesis of thiourea additives. The GPE with OPPT thiourea additive achieved a good efficiency of 5.7%.
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