The development of highly active and stable oxygen evolution reaction (OER) electrocatalysts is crucial for improving the efficiency of water splitting and metal-air battery devices. Herein, an efficient strategy is demonstrated for making the oxygen vacancies dominated cobalt-nickel sulfide interface porous nanowires (NiS /CoS -O NWs) for boosting OER catalysis through in situ electrochemical reaction of NiS /CoS interface NWs. Because of the abundant oxygen vacancies and interface porous nanowires structure, they can catalyze the OER efficiently with a low overpotential of 235 mV at j = 10 mA cm and remarkable long-term stability in 1.0 m KOH. The home-made rechargeable portable Zn-air batteries by using NiS /CoS -O NWs as the air-cathode display a very high open-circuit voltage of 1.49 V, which can maintain for more than 30 h. Most importantly, a highly efficient self-driven water splitting device is designed with NiS /CoS -O NWs as both anode and cathode, powered by two-series-connected NiS /CoS -O NWs-based portable Zn-air batteries. The present work opens a new way for designing oxygen vacancies dominated interface nanowires as highly efficient multifunctional electrocatalysts for electrochemical reactions and renewable energy devices.
The development of highly efficient bifunctional catalysts for oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) is crucial for improving the efficiency of the Zn-air battery. Herein, we report porous NiO/CoN interface nanowire arrays (PINWs) with both oxygen vacancies and a strongly interconnected nanointerface between NiO and CoN domains for promoting the electrocatalytic performance and stability for OER and ORR. Extended X-ray absorption fine structure spectroscopy, electron spin resonance, and high-resolution transmission electron microscopy investigations demonstrate that the decrease of the coordination number for cobalt, the enhanced oxygen vacancies on the NiO/CoN nanointerface, and strongly coupled nanointerface between NiO and CoN domains are responsible for the good bifunctional electrocatalytic performance of NiO/CoN PINWs. The primary Zn-air batteries, using NiO/CoN PINWs as an air-cathode, display an open-circuit potential of 1.46 V, a high power density of 79.6 mW cm, and an energy density of 945 Wh kg. The three-series solid batteries fabricated by NiO/CoN PINWs can support a timer to work for more than 12 h. This work demonstrates the importance of interface coupling and oxygen vacancies in the development of high-performance Zn-air batteries.
Simultaneous
realization of improved activity, enhanced stability,
and reduced cost remains a desirable yet challenging goal in the search
of electrocatalysis oxygen evolution reaction (OER) in acid. Herein,
we report a novel strategy to prepare iridium single-atoms (Ir-SAs)
on ultrathin NiCo2O4 porous nanosheets (Ir–NiCo2O4 NSs) by the co-electrodeposition method. The
surface-exposed Ir-SAs couplings with oxygen vacancies (VO) exhibit boosting the catalysts OER activity and stability in acid
media. They display superior OER performance with an ultralow overpotential
of 240 mV at j = 10 mA cm–2 and
long-term stability of 70 h in acid media. The TOFs of 1.13 and 6.70
s–1 at an overpotential of 300 and 370 mV also confirm
their remarkable performance. Density functional theory (DFT) calculations
reveal that the prominent OER performance arises from the surface
electronic exchange-and-transfer activities contributed by atomic
Ir incorporation on the intrinsic VO existed NiCo2O4 surface. The atomic Ir sites substantially elevate
the electronic activity of surface lower coordinated Co sites nearby
VO, which facilitate the surface electronic exchange-and-transfer
capabilities. With this trend, the preferred H2O activation
and stabilized *O have been reached toward competitively lower overpotential.
This is a generalized key for optimally boosting OER performance.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.