In situ H2O2 generation methods in the context of enzyme biocatalysis

Peroxide-Mediated Oxygenation of Organic Compounds by Fungal Peroxygenases

“…Only a small group of UPOs have been demonstrated to catalyze a range of oxygenations at different types of carbons, which is reflected by numerous original papers (>80) and review articles dealing with UPO-catalyzed conversions since their discovery in 2004; some relevant review articles covering, in addition to biochemical and synthetic, also biosensor-related findings can be found in [ 2 , 7 , 10 , 24 , 25 , 29 , 30 , 31 , 93 , 94 , 95 , 96 , 97 , 98 , 99 , 100 , 101 ].…”

Recent Progress and Prospects in Catalytic Water Treatment

“…Once formed, H2O2 serves as substrate to catalyze an enzyme reaction (Figure 84). 911 The slow step of the process is photoactivation process which can be speed up by increasing light intensity and/or the amount of the photocatalyst. 912 Such concept can be powerful due to its simplicity and cost-efficiency.…”

Plasma‐driven biocatalysis: In situ hydrogen peroxide production with an atmospheric pressure plasma jet increases the performance of OleTJE when compared to adding the same molar amount of hydrogen peroxide in bolus

“…GC has been the standard analysis method to examine substrates and products for OleT JE reactions. [3,5,15,16,20] Substrate and products were all identified using authentic standards. The fatty alcohol side reaction products of OleT JE are also monitored to look for an advantage in the reaction chemistry of this method.…”

“…It is worth noting that the TONs for OleT JE are much lower than its common peroxidase counterparts (hundreds as opposed to tens and hundreds of thousands). [ 16 ] Moreover, these reactions require the addition of a separate component (enzyme or flavin) to the reaction solution, which will increase the cost of production in the long run. An alternative method for in situ generation of H 2 O 2 without the need for exogenous additives is through the application of atmospheric pressure plasmas.…”