Metal
organic frameworks (MOFs) have been explored as adsorption
materials owing to their diversity, controllable structure, high specific
surface area, and abundant active sites. However, the shaping of MOFs
has become a critical issue hindering their commercial application.
A binder or high pressure is commonly used in traditional powder shaping,
causing pores to be blocked or collapsed and porosity to be decreased,
eventually leading to the degradation of adsorption performance. In
this paper, Zr-MOFs were in situ grown on a columnar activated carbon
(CAC) matrix, and a series of Zr-MOFs/CAC composites were prepared.
The adsorption properties for SO2 and NO2 were
measured by dynamic adsorption tests, and the Wheel–Jonas model
was used to calculate the saturated adsorption capacity. Abundant
mesopores can be formed between MOF crystals and activated carbon
particles, and the mesoporosity of Zr-MOFs/CAC composites reached
over 50%. Owing to the abundant mesoporous, increased activated sites
as well as the synergistic effect between MOFs and activated carbon,
the as-obtained HP-Zr-MOFs/CAC exhibited the best adsorption performance
both for SO2 and NO2, which are 34.2 and 17.4
mg g–1, respectively, while the adsorption capacities
of CAC for SO2 and NO2 are 20.9 and 6.6 mg g–1, respectively. The outstanding performance and facile
synthesis process of HP-Zr-MOFs/CAC composites could provide ideas
to develop other hierarchical porous MOFs/activated carbon composites.