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The NiCo2O4 nanowires and rGO hybrid nanostructure was constructed on carbon fibers (NiCo2O4/rGO/CF) via a hydrothermal method.

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Metal organic frameworks (MOFs) have been explored as adsorption materials owing to their diversity, controllable structure, high specific surface area, and abundant active sites. However, the shaping of MOFs has become a critical issue hindering their commercial application. A binder or high pressure is commonly used in traditional powder shaping, causing pores to be blocked or collapsed and porosity to be decreased, eventually leading to the degradation of adsorption performance. In this paper, Zr-MOFs were in situ grown on a columnar activated carbon (CAC) matrix, and a series of Zr-MOFs/CAC composites were prepared. The adsorption properties for SO2 and NO2 were measured by dynamic adsorption tests, and the Wheel–Jonas model was used to calculate the saturated adsorption capacity. Abundant mesopores can be formed between MOF crystals and activated carbon particles, and the mesoporosity of Zr-MOFs/CAC composites reached over 50%. Owing to the abundant mesoporous, increased activated sites as well as the synergistic effect between MOFs and activated carbon, the as-obtained HP-Zr-MOFs/CAC exhibited the best adsorption performance both for SO2 and NO2, which are 34.2 and 17.4 mg g–1, respectively, while the adsorption capacities of CAC for SO2 and NO2 are 20.9 and 6.6 mg g–1, respectively. The outstanding performance and facile synthesis process of HP-Zr-MOFs/CAC composites could provide ideas to develop other hierarchical porous MOFs/activated carbon composites.

The filter paper and activated carbon which filled inside the gas filter have porous media characteristics. In order to study the flow field structure in the filter layer and the activated carbon layer, Computational Fluid Dynamics method is used to simulate the aerodynamic characteristics of a simplified gas filter. The inertial and viscosity parameters of porous media are solved by Forchheimer equation. The three-dimensional N-S equation and the modified low Reynolds number k-ε turbulence model are adopted to analyze the influence of the explosion-proof plate on the gas filter's aerodynamic characteristics. The results showed that the air age in the upstream of the activated carbon plates was small, which easily caused the rapid penetration of the Poisonous gas. And in the downstream and around of the activated carbon plates, the air age is larger, formed dead zone, the utilization rate of activated carbon is lower. The explosion-proof plate increases the pressure drop of the gas filter, the air age distribution in the filter layer is more uniform and the utilization rate of filter paper is improved. However, the explosion-proof plate has little influence on the flow field structure of the activated carbon layer.

The development of fluorescent probes for detecting nerve agents has been the main concern focus of research because of their lethal toxicity for humans. Herein, a probe (PQSP) based on the quinoxalinone unit and the styrene pyridine group was synthesized and could visually detect a sarin simulant diethyl chlorophosphate (DCP) with excellent sensing properties in solution and solid states. Interestingly, PQSP showed an apparent intramolecular charge-transfer process by catalytic protonation after reacting with DCP in methanol, accompanied with the aggregation recombination effect. The sensing process was also verified by nuclear magnetic resonance spectra, scanning electron microscopy, and theoretical calculations. In addition, the papered test strips of loading probe PQSP exhibited an ultrafast response time within 3 s and high sensitivity with a limit of detection of 3 ppb for the detection of DCP vapor. Therefore, this research provides a designed strategy for developing the probes with dual-state emission fluorescence in solution and solid states for detecting DCP sensitively and rapidly, which can be fabricated as chemosensors to visually detect nerve agents in practice.