Avalanche injection of hot electrons into the insulator of an MOS capacitor has been used to study electron trapping in SiO2. Oxides formed by thermal oxidation in dry O~, 02 -5 HC1, 02 -5 I-I20, steam, and chemical vapor-deposited (CVD) SiO2 were subjected to avalanche charging. Pure, dry thermal SiO2 was found to trap up to 2.6 X 10 TM e/cm 2. The trapping efficiency of SiO~ varied by three orders of magnitude, depending on forming and annealing conditions.) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 129.115.103.99 Downloaded on 2015-06-15 to IP
ABSTRACTThe electrical conductivity of fl-PbF2 in single crystal and pressed pellets was measured by a-c bridge techniques. Aliovalent cation fluoride doping was used to elucidate the conductivity mechanism in the extrinsic region, 25~176Conduction was shown to be via fluoride ion vacancies. Potassium fluoride dopant increased the ionic conductivity of ~-PbFe from 5 • 10 -7 to 1 • 10 -8 ohm-~-cm -J at room temperature. However, galvanic cells utilizing the higher conductivity of the doped material failed due to formation of a passivation layer of pure ~-PbF2 at the anode/electrolyte interface. * Electrochemical Society Active Member.