Hydrothermal synthesis and structural characterization of the first indium phosphite In2(HPO3)3(H2O)

Octahedral–tetrahedral framework structures of InAsO4·H2O and PbIn(AsO4)(AsO3OH)

“…Compound (I) represents the ®rst inorganic compound containing an In 2 O 8 (H 2 O) 2 dimer. A closely related, equally unique, In 2 O 9 (H 2 O) dimer is present in In 2 (HPO 3 ) 3 (H 2 O) (Yi et al, 2005). In contrast, water-free In 2 O 10 dimers have been reported in several indium compounds, such as -LiIn(MoO 4 ) 2 (Velikodnyi et al, 1980), CaIn 2 (PO 4 ) 2 (HPO 4 ) (Tang & Lachgar, 1996), Na 3 In 2 (PO 4 ) 3 and Na 3 In 2 (AsO 4 ) 3 (Lii & Ye, 1997), and In 2 O(PO 4 ) (Thauern & Glaum, 2004).…”

Synthesis, characterization and magnetic property of a new 3D iron phosphite: |C4N3H14|[Fe3(HPO3)4F2(H2O)2] with intersecting channels

“…In the literature, a large number of gallium- [26], indium- [27] and iron- [28] phosphates; as well as, zinc- [14,15,29] and indium- [30] phosphites have been reported. In order to expand the field of research pertaining to iron phosphite materials with excellent properties, our group has chosen to explore the design and synthesis of novel open architectures by introducing the F À anion as mineralizer and organic template as part of our design strategy.…”

Organic template-directed indium phosphite-oxalate hybrid material: Synthesis and characterization of a novel 3D |C6H14N2|[In2(HPO3)3(C2O4)] compound with intersecting channels

“…During the last few years, our group has worked on the synthesis and structural investigation of indium phosphates and phosphites [24,9]. In order to expand the field of research pertaining to indium phosphite materials, our group has chosen to explore the design and synthesis of novel open architectures by introducing the oxalate ligand as part of our design strategy.…”

“…Nevertheless, only a few metal phosphite-oxalates pertaining to iron and lanthanide (Ln = Pr, Nd, Sm-Lu) have been reported [21][22][23]. However, to the best of our knowledge, none of indium phosphite-oxalates have been reported in the literature.During the last few years, our group has worked on the synthesis and structural investigation of indium phosphates and phosphites [24,9]. In order to expand the field of research pertaining to indium phosphite materials, our group has chosen to explore the design and synthesis of novel open architectures by introducing the oxalate ligand as part of our design strategy.…”

“…Interestingly, only a limited number of indium phosphite materials have been reported in the literature. The first indium phosphite material synthesized by the hydrothermal technique was In 2 (HPO 3 ) 3 (H 2 O) [9]. Wang [11].…”