Synthesis, characterization and magnetic property of a new 3D iron phosphite: |C4N3H14|[Fe3(HPO3)4F2(H2O)2] with intersecting channels

Fluorinated mixed valence Fe(ii)–Fe(iii) phosphites with channels templated by linear tetramine chains. Structural and magnetic implications of partial replacement of Fe(ii) by Co(ii)

“…Several attempts to replace the organic template by mobile cations such as Li + or Na + were made in order to obtain a new phase with conductive properties. However, hydroxides from lithium and/or sodium sources seem to merely basify the dissolution, causing the decomposition of the organic molecule in such a way that iron(III) phosphite 35 crystallizes.…”

Solvothermal Synthesis and Characterizations of Two Isomerism Cobalt Phosphite‐Oxalates with Varying Dimensions Using the Same Template from in situ Reaction

“…Many research are concerned about the open‐framework materials in the past several decades, due to its fascinating structures and the widely potential applications in catalysis, absorption and proton conduction, etc . Phosphorus‐based metal oxide (MPO) are one of the most important inorganic materials, especially on the investigation of pseudo pyramidal phosphite group [HPO 3 ] 2– instead of tetrahedral phosphate group [PO 4 ] 3– as a basic building unit to combine the structure . To rich and complicate the structures of metal phosphites, many attempts have made it possible by using various ligands .…”

High-throughput syntheses of iron phosphite open frameworks in ionic liquids

“…Among these materials, iron phosphites occupied a considerable position because of its rich diversity of structures and special magnetic properties. [50], and a new 3D iron phosphite with an antiferromagnetic property. Typically, metal phosphites were synthesized under hydrothermal or solvothermal conditions.…”