“…Related sulfide chimneys, mounds and sediments contain generally less REEs than the nearby marine sediments (Courtois and Clauer, 1980;Clauer et al, 1984;Marchig et al, 1986;German et al, 1995German et al, , 1997, but the Fe-oxi-hydroxides are enriched in REEs relative to sulfides due to particle-surface adsorption processes and/or direct co-precipitation of Fe-rich phases (e.g., Fleet, 1984;Mills et al, 1993;Mills and Elderfield, 1995;Pichler and Veizer, 1999). For instance, oxides of active and relict chimneys (26°N Mid-Atlantic Ridge) yield a typical REE hydrothermal signature, with concentrations that are two orders of magnitude higher than those of the associated sulfide minerals (e.g., Mills et al, 2001).…”