Hydroformylation Oxo Synthesis, Roelen Reaction

Cornils, B.

doi:10.1007/978-3-642-67452-5_1

Cited by 74 publications

(5 citation statements)

References 586 publications

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“…29 Both in the rhodium-and the platinum/tin-catalysed hydroformylation phosphines have proven to be superior to other donor ligands, such as nitrogen-or arsine-containing compounds. 15,20,30,31 Owing to their extensive use in catalysis, the influence of phosphine structure on catalytic performance has been studied in great detail. 2 Tolman introduced the concept of the cone angle θ and the electronic parameter χ to classify phosphorus ligands with respect to their steric bulk and phosphine basicity.…”

Section: Introductionmentioning

confidence: 99%

Wide bite angle amine, arsine and phosphine ligands in rhodium- and platinum/tin-catalysed hydroformylation †

Veen

Keeven

Kamer

et al. 2000

J. Chem. Soc., Dalton Trans.

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Section: Introductionmentioning

confidence: 99%

Wide bite angle amine, arsine and phosphine ligands in rhodium- and platinum/tin-catalysed hydroformylation †

Veen

Keeven

Kamer

et al. 2000

J. Chem. Soc., Dalton Trans.

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“…[47 -50]). Die Anlagen der IG in Leuna und Ludwigshafen wurden spä-ter die Keimzellen des BASF-Oxoverfahrens [51,52], worauf neben konstruktiven und chemischen Details auch die Kontinuität der Bearbeiter und Erfinder von der IG bis zu den BASF-Patentanmeldungen hinweist, beispielsweise in Person der Drs. Nienburg und Gemassmer, die in den alliierten Unterlagen häufig als Partner Roelens bei den gemeinsamen Arbeitsbesprechungen genannt werden [53].…”

Section: Technik Der Frühen Oxosyntheseunclassified

75 Years of Hydroformulation – Oxo Reactors and Oxo Plants of Ruhrchemie AG and Oxea GmbH from 1938 to 2013

Hibbel¹,

Wiebus

Cornils³

2013

Chemie Ingenieur Technik

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Years of Hydroformulation -Oxo Reactors and Oxo Plants of Ruhrchemie AG and Oxea GmbH from 1938 to 2013The hydroformulation reaction, also known as oxo synthesis or Roelen reaction, is the atom-efficient and metal-catalyzed addition of the constituents of synthesis gas, H 2 and CO, to the double bonds of alkenes. This reaction has been discovered in 1938 by Otto Roelen in the laboratories of the chemical company Ruhrchemie AG. After filing the patent application efforts to scale up the process to technical scale have been started. However, they have only partly been successful for the plants of the Ruhrchemie AG Oberhausen and its cooperation partner I.G. Farbenindustrie AG due to the difficult circumstances. After World War II the Ruhrchemie process based on cobalt catalysts and the Ruhrchemie/Rhône-Poulenc process as the first important aqueous two-phase processes with rhodium catalysts became the most important homogenously catalyzed chemical processes.

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“…• The hydroformylation of ethylene oxide [35] • The oxidation of propene to acrolein, followed by hydration (Degussa) [36] • Sugar fermentation (Du Pont) [37].…”

Section: Catalysis For Environmental Protection: Future Prospectsmentioning

confidence: 99%

Catalysis in Environmental Protection

Keim

2008

Handbook of Heterogeneous Catalysis

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The sections in this article are Introduction How Novel is Environmental Catalysis? Environmental Catalysis: Potential and Opportunities Catalysis for Environmentally Benign Products and Processes Products and Environmental Concern Processes and Environmental Compatibility Catalysis for Environmental Protection: Future Prospects

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Hydroformylation Oxo Synthesis, Roelen Reaction

Cited by 74 publications

References 586 publications

Wide bite angle amine, arsine and phosphine ligands in rhodium- and platinum/tin-catalysed hydroformylation †

Wide bite angle amine, arsine and phosphine ligands in rhodium- and platinum/tin-catalysed hydroformylation †

75 Years of Hydroformulation – Oxo Reactors and Oxo Plants of Ruhrchemie AG and Oxea GmbH from 1938 to 2013

Catalysis in Environmental Protection

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