“…The formation of the normal-plane DLC by PLD is largely explained by the subplantation process because of the forwarddirected, high kinetic energy, and ionized carbon species produced [12,13]. However, when the graphite target was irradiated by UV laser pulses, DLC was found in the top layer of highly oriented pyrolytic graphite (HOPG), which contained as much as 50% sp 3 of the hybrid-states carbon [14,15].…”