High-performance SnSb@rGO@CMF composites as anode material for sodium-ion batteries through high-speed centrifugal spinning

Jia, Hao; Dirican, Mahmut; Zhu, Jiadeng; Chen, Chen; Yan, Chaoyi; Zhu, Pei; Wang, Yongdong; Guo, Jiansheng; Caydamli, Yavuz; Zhang, Xiangwu

doi:10.1016/j.jallcom.2018.04.141

Cited by 34 publications

(17 citation statements)

References 34 publications

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“…[21][22][23][24] Till now, a variety of fibers have been successfully fabricated by centrifugal spinning, including polymer based fibers, 25,26 inorganic metal oxide fiber, 27,28 and composite fibers. 29,30 These fibers involved in the applications of tissue engineering, energy conversion/storage, and filtration. 31 Our group focuses on the development of centrifugally spun ultrafine fibers from bio-based polymers, including the regenerated silk fibroin nanofiber, 32 highly porous ethyl cellulose fibers, 33 and alginate-riched nanofibers.…”

Section: Introductionmentioning

confidence: 99%

“…Centrifugal spinning, which originated from cotton candy machine, received a great attention over the past few years due to the capability for nanofiber production with advantages of no polar requirement for spinning solution/melt, high productivity of fibers, controllable fluffy degree of fibrous membranes and orientation of fibers 21–24 . Till now, a variety of fibers have been successfully fabricated by centrifugal spinning, including polymer based fibers, 25,26 inorganic metal oxide fiber, 27,28 and composite fibers 29,30 . These fibers involved in the applications of tissue engineering, energy conversion/storage, and filtration 31 .…”

Section: Introductionmentioning

confidence: 99%

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Centrifugally spun starch/polyvinyl alcohol ultrafine fibrous membrane as environmentally‐friendly disposable nonwoven

Liu

et al. 2021

J of Applied Polymer Sci

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We developed a new environmentally-friendly disposable nonwoven based on centrifugally spun ST/PVA ultrafine fibrous membrane in this research. The effects of ST/PVA ratio as well as formic acid post-treatment on thermal properties, tensile strength, and disposability of fibrous membranes were studied.To observe the morphology and chemical structures changing of fibers during fabrication and post-treatment, the obtained fibers were characterized by scanning electron microscopy, x-ray diffraction, and Fourier transform infrared spectroscopy. The fibrous membranes with uniform fiber diameters and excellent disposability properties were formed. The ST/PVA ratio of fibers was optimized according to the disposability and tensile strength of the fibrous membranes. Disintegration of untreated and post-treatment fibrous membrane with ST/PVA ratio of 3/1 was over 80% and 40%, respectively, and the tensile strength was improved over two times comparing with pure starch fibrous membrane.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Centrifugally spun starch/polyvinyl alcohol ultrafine fibrous membrane as environmentally‐friendly disposable nonwoven

Liu

et al. 2021

J of Applied Polymer Sci

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“…In this format, the composite of C/Sn/reduced graphene oxide (RGO) possesses a higher initial reversible capacity of 476.2 mAh g −1 with a CE of 70.3% reported by Dong et al Various methods have been proposed to make Sn nanoparticles with Sb element over graphene sheets to explore the efficient way to buffer the mechanical stress, improve the conductivity, and occur a high capacity of the composites since graphene is more flexible and bendable . In fact, these nanocomposites also display their versatility as a high‐capacity anode for SIBs . The summary of carbon supported Sn composite electrochemical properties is given in Table 1 .…”

Section: Carbon Supported Tin‐based Composite For Sibsmentioning

confidence: 99%

Carbon‐Based Alloy‐Type Composite Anode Materials toward Sodium‐Ion Batteries

Yang

Ilango

Wang

et al. 2019

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In the scenario of renewable clean energy gradually replacing fossil energy, grid‐scale energy storage systems are urgently necessary, where Na‐ion batteries (SIBs) could supply crucial support, due to abundant Na raw materials and a similar electrochemical mechanism to Li‐ion batteries. The limited energy density is one of the major challenges hindering the commercialization of SIBs. Alloy‐type anodes with high theoretical capacities provide good opportunities to address this issue. However, these anodes suffer from the large volume expansion and inferior conductivity, which induce rapid capacity fading, poor rate properties, and safety issues. Carbon‐based alloy‐type composites (CAC) have been extensively applied in the effective construction of anodes that improved electrochemical performance, as the carbon component could alleviate the volume change and increase the conductivity. Here, state‐of‐the‐art CAC anode materials applied in SIBs are summarized, including their design principle, characterization, and electrochemical performance. The corresponding alloying mechanism along with its advantages and disadvantages is briefly presented. The crucial roles and working mechanism of the carbon matrix in CAC anodes are discussed in depth. Lastly, the existing challenges and the perspectives are proposed. Such an understanding critically paves the way for tailoring and designing suitable alloy‐type anodes toward practical applications.

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“…In recent years, Sn‐based anode materials gained extensive research attention due to their high theoretical capacities in both SIBs and LIBs . Nevertheless, the major challenge for the practical use of Sn‐based anode materials is their poor cycling performance caused by the severe volume expansion.…”

Section: Introductionmentioning

confidence: 99%

“…It is experimentally reported that the volume of Sn can expand up to 420 % after reacting with Na and the formed Na 15 Sn 4 phase would easily cause electrode destabilization . Hence, in recent years, many efforts have been devoted to accommodating the deleterious volumetric expansion of Sn‐based anode materials by introducing additional metal elements to form bimetal oxides ,. It is found that compared to pure single tin oxide (SnO 2 ), its derivative bimetal oxides ( e. g .…”

Section: Introductionmentioning

confidence: 99%

Advanced ZnSnS₃@rGO Anode Material for Superior Sodium‐Ion and Lithium‐Ion Storage with Ultralong Cycle Life

et al. 2018

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A novel and facile approach has been utilized to synthesize zinc tin sulfide@reduced graphene oxide (ZnSnS 3 @rGO) through aqueous reaction of Na 2 SnO 3 and Zn(CH 3 COO) 2 , combined with a subsequent solvothermal reaction and an annealing process. The as-prepared ZnSnS 3 @rGO nanocomposite exhibited an excellent sodium-and lithium-ion-storage performance with large specific capacity, high rate capability, and ultralong cycle life. When used in Na-ion cells, the ZnSnS 3 @rGO nanocomposite delivered a capacity of 472.2 mAh g À 1 at 100 mA g À 1 and retained a specific capacity of 401.2 mAh g À 1 after 200 cycles. In Li-ion cells, the ZnSnS 3 @rGO nanocomposite delivered a capacity of 959.2 mAh g À 1 at a current density of 100 mA g À 1 and maintained a specific capacity of 551.3 mAh g À 1 at a high current density of 1 A g À 1 upon 500 cycles. The electrochemical performance results reveal that the integration of uniformly dispersed metal elements and an interconnected carbon matrix could help release the stress of volumetric excursion and provide fast electron/ion transport, leading to a remarkable electrochemical performance.

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High-performance SnSb@rGO@CMF composites as anode material for sodium-ion batteries through high-speed centrifugal spinning

Cited by 34 publications

References 34 publications

Centrifugally spun starch/polyvinyl alcohol ultrafine fibrous membrane as environmentally‐friendly disposable nonwoven

Centrifugally spun starch/polyvinyl alcohol ultrafine fibrous membrane as environmentally‐friendly disposable nonwoven

Carbon‐Based Alloy‐Type Composite Anode Materials toward Sodium‐Ion Batteries

Advanced ZnSnS₃@rGO Anode Material for Superior Sodium‐Ion and Lithium‐Ion Storage with Ultralong Cycle Life

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High-performance SnSb@rGO@CMF composites as anode material for sodium-ion batteries through high-speed centrifugal spinning

Cited by 34 publications

References 34 publications

Centrifugally spun starch/polyvinyl alcohol ultrafine fibrous membrane as environmentally‐friendly disposable nonwoven

Centrifugally spun starch/polyvinyl alcohol ultrafine fibrous membrane as environmentally‐friendly disposable nonwoven

Carbon‐Based Alloy‐Type Composite Anode Materials toward Sodium‐Ion Batteries

Advanced ZnSnS3@rGO Anode Material for Superior Sodium‐Ion and Lithium‐Ion Storage with Ultralong Cycle Life

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Product

Resources

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Advanced ZnSnS₃@rGO Anode Material for Superior Sodium‐Ion and Lithium‐Ion Storage with Ultralong Cycle Life