High ionic conductivity and mechanical strength of solid polymer electrolytes based on NBR/ionic liquid and its application to an electrochemical actuator

Cho, Misuk; Seo, Hyunjoo; Nam, Jedo; Choi, Hyoukryeol; Koo, Jachoon; Lee, Youngkwan

doi:10.1016/j.snb.2007.05.032

Cited by 50 publications

(45 citation statements)

References 15 publications

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“…2, 3, 4). This could be due to the interactions between functional groups present on the carbon black surface and ionic liquids similar to those observed for BmiTFSI and carbon nanotubes [10].…”

Section: Resultsmentioning

confidence: 66%

“…Owing to their unique properties such as thermal, chemical, and electrochemical stability, low vapor pressure, and high ionic conductivity, ILs have attracted much attention for applications in polymer science [1,7,8], particularly toward developing conducting polymer composites. ILs have excellent ionic conductivity up to their decomposition temperature, which enables them to play an important role in electrolyte matrices [6,9,10]. Recently, ILs have been widely used to improve the degree of dispersion of nanoparticles in polymers, particularly in elastomers [11][12][13].…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Ionic liquids as coagents for sulfur vulcanization of butadiene–styrene elastomer filled with carbon black

Maciejewska

Zaborski

2018

Polym. Bull.

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The aim of this work was to study the activity of several alkylimidazolium salts of bis(trifluoromethylsulfonyl)imides to obtain a very fast vulcanization of the butadiene-styrene (SBR) elastomer. Ionic liquids (ILs) such as alkylimidazolium salts with ethyl-, propyl-, butyl-, hexyl-, decyl-, dodecyl-, and hexadecyl chains in the cation together with nanosized zinc oxide are used to develop elastomer composites with very short vulcanization time and a reduced amount of vulcanization activator. In this article, we discuss the effect of the ILs with respect to the length of alkyl chain in their cation on the vulcanization kinetics of rubber compounds. The influence of ILs on the crosslink density as well as the mechanical properties of the vulcanizates and their resistance to thermo-oxidative and UV aging were also studied. ILs resulted in a shortened optimal vulcanization time and reduced the onset vulcanization temperature compared to zinc oxide containing rubber compound. This is very important from a technological point of view. A considerable increase in the crosslink density of vulcanizates was also observed.

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Section: Resultsmentioning

confidence: 66%

Section: Introductionmentioning

confidence: 99%

Ionic liquids as coagents for sulfur vulcanization of butadiene–styrene elastomer filled with carbon black

Maciejewska

Zaborski

2018

Polym. Bull.

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“…This membrane can be obtained by solvent evaporation and UV irradiation (Blonsky & Meridian 1997;Heuer et al 2002;Sansinena et al 1997;Song et al 2002), or by formation of interpenetrated networks (Cho et al 2007;Plesse et al 2005;Vidal et al 2009;Vidal et al 2003): the two films of CP are generated by chemical polymerization on the external part of the film membrane.…”

Section: Three-layer Structurementioning

confidence: 99%

Biomimetic Sensing – Actuators Based on Conducting Polymers

Arias‐Pardilla¹,

Otero²,

Martínez³

et al. 2012

Aspects on Fundaments and Applications of Conducting Polymers

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“…But using this configuration it is also possible to obtain movement outside a liquid electrolyte media using an ionic conducting membrane to separate the two films of conducting polymers. This membrane can be obtained by solvent evaporation and UV irradiation (Blonsky & Meridian, 1997;Heuer et al, 2002;Sansinena et al, 1997;Song et al, 2002), or by formation of interpenetrated networks (Cho et al, 2007;Plesse et al, 2005;Vidal et al, 2009;Vidal et al, 2003). In this case, the two conducting polymer films are generated by chemical polymerization on the external part of the membrane.…”

Section: Bending Artificial Musclesmentioning

confidence: 99%