We report on the reduction of defect densities in non-polar a-plane GaN films over r-plane sapphire achieved by epitaxial laterally overgrowth (ELOG) approach. A mask pattern was used to produce ELOG GaN with wing region width of about 30µm. Based on transmission electron microscopy (TEM) results, the window regions have stacking faults density of ∼10 6 cm -1 and threading dislocation density of ∼10 10 cm -2 . Both ELOG Ga-face and N-face wing regions have stacking fault density of ~10 5 cm -1 , and dislocation density less than 10 8 cm -2. Cathodoluminescence studies reveal the difference in defect densities between N-faced and Ga-faced wings. GaN-based UV light-emitting diode formed on Ga-faced wing shows stronger quantum well emission and weaker parasitic emission than that formed on N-faced wing. . III-N quantum well (QW) structures grown over conventional (0001) orientation are subjected to significant quantum-confined Stark effect (QCSE) caused by strong polarization fields. The QCSE results in carrier separation because of band bending, thereby reducing device efficiency of light emitting devices [4,5]. Recently, several groups including ours have reported the growth of non-polar (11-20) plane GaN films over (1-102) r-plane sapphire substrates. It has been demonstrated that a-plane QW structures grown over r-plane sapphires are free from polarization-induced internal electrostatic field [6][7][8][9]. Thus, there has been considerable interest in the growth of high quality nitride films and heterostructures with non-polar orientations for the development of high efficiency light emitters.