Gold-catalyzed oxidative aminoesterification of unactivated alkenes

Feige, Pascal; Haro, Teresa de; Rusconi, Giulia; Merino, Estı́baliz; Nevado, Cristina

doi:10.1007/s00706-018-2144-8

Cited by 6 publications

(1 citation statement)

References 58 publications

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“…In 2018, a similar study using DMF as the nucleophile in the presence of water led to the formate product (Scheme 87B). 201 Notably, in that study, in addition to Selectfluor, several PIDA variants containing different carboxylates were also employed as oxidants, which led to the formation of aminoesterification products featuring an ester group rather than formate.…”

Section: Selectfluor and Other Electrophilic Fluorine Reagents As Oxi...mentioning

confidence: 99%

Homogeneous Gold-Catalyzed Oxidation Reactions

et al. 2021

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Homogeneous gold catalysis has experienced extraordinary development since the dawn of this millennium. Oxidative gold catalysis is a vibrant and fertile subfield and has over the years delivered a diverse array of versatile synthetic methods of exceptional value to synthetic practices. This review aims to cover this topic in a comprehensive manner. The discussions are organized by the mechanistic aspects of the metal oxidation states and further by the types of oxidants or oxidizing functional groups. Synthetic applications of oxidative gold catalysis are also discussed. CONTENTS 4.5. Oxidation of Sulfides and Other Functional Groups 9029 5. Conclusion and Outlook 9030 Author Information 9030 Corresponding Author 9030 Authors 9030 Author Contributions 9030 Notes 9030 Biographies 9030 Acknowledgments 9031 References 9031

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Section: Selectfluor and Other Electrophilic Fluorine Reagents As Oxi...mentioning

confidence: 99%

Homogeneous Gold-Catalyzed Oxidation Reactions

et al. 2021

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Transition‐Metal‐Catalyzed Aminooxygenation of Alkenes

Chemler¹,

Chen²,

Karyakarte³

et al. 2021

Organic Reactions

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Alkene aminooxygenation reactions provide vicinal amino alcohol derivatives, moieties that frequently appear in catalysts, drugs, and other valuable molecules. This Chapter reviews transition‐metal‐catalyzed aminooxygenations of alkenes and aims to serve as a guide in the selection of appropriate reagents and procedures for specific substrate classes and desired transformations. Inter‐ and intramolecular aminooxygenation reactions catalyzed by osmium, palladium, platinum, gold, copper, iron, iridium, rhodium, ruthenium, and manganese are presented, as is a discussion of the factors involved in reactivity and selectivity. A brief section on non‐metal catalyzed alkene aminohydroxylation is also included. A complete set of alkene aminooxygenation reactions through mid‐2020 is provided in the Tabular Survey.

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Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents

Yoshimura,

Zhdankin

2024

Chem. Rev.

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Gold-catalyzed oxidative aminoesterification of unactivated alkenes

Cited by 6 publications

References 58 publications

Homogeneous Gold-Catalyzed Oxidation Reactions

Homogeneous Gold-Catalyzed Oxidation Reactions

Transition‐Metal‐Catalyzed Aminooxygenation of Alkenes

Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents

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