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A pyridine adduct of bis(di-iso-butyldithiocarbamato-S,S′)cadmium(II): Multinuclear (13C, 15N, 113Cd) CP/MAS NMR spectroscopy, crystal and molecular structure, and thermal behaviour

“…The line width of the para-carbon resonance is not sensitive to this type of molecular dynamics because the electronic environment around the para-carbon atom is basically constant in the course of the ring-tumbling. The same motional behaviour of the coordinated py molecules has been previously observed for bis(diethyldithiocarbamato-S,S 0 )(pyridine)zinc(II) [32] and different clathrates of this adduct, which was solvated with various chlorohydrocarbons: CH 2 Cl 2 and CHCl 3 [33], CCl 4 [34,35] (but not in the cases of solvated forms of the adduct with 1,2-C 2 H 4 Cl 2 [36], benzene [37] or pyridine [38]). Fig.…”

“…5b). The same orientation of the py-ring plane was previously observed in the solvated form of another pyridine adduct of zinc(II) diethyldithiocarbamate, [Zn (C 5 [34,35].…”

Bis(1,2,3,4-tetrahydroquinoline-1-thiocarbonyl) disulfide

“…1. The S-S bond distance of 1.9958 (6) Å is close to the related literature value (Ivanov et al, 2003;Jian et al, 1999;Fun et al, 2001).…”

“…For preparation of the title compound, see: Garg et al (1993). For related structures, see: Ivanov et al (2003); Jian et al (1999); Fun et al (2001). For ring-puckering parameters, see: Nardelli (1983).…”

Crystal structure of tetraisobutylthiuram disulfide

“…Values for and for structures in the Cambridge Structural Database (Web CSD v1.1.1; Groom et al, 2016) were determined using Mercury (Macrae et al, 2008). These structures are: METHUS (Marøy, 1965), METHUS01 (Ymé n, 1983), METHUS02 (Wang et al, 1986), METHUS03 (Wang & Liao, 1989), METHUS04 (Wang & Liao, 1989), ETHUSS (Karle et al, 1967) ETHUSS01 (Wang et al, 1986), ETHUSS02 (Wang & Liao, 1989), ETHUSS03 (Wang & Liao, 1989), ETHUSS04 (Shi & Wang, 1992), ETHUSS05 (Hu, 2000), HIQJUM (Jian et al, 1999), HIQJUM01 (Yu & Wang, 2003), JECYAZ (Kumar et al, 1990), TIBFEQ (Zhai et al, 2007), ZEMPUC (Hall & Tiekink, 1995), KAZHEA (Karim et al, 2012), NELTUT (Fun et al, 2001), XEBJOF (Ajibade et al, 2012), JAXPOO (Raya et al, 2005), CAPLEK (Williams et al, 1983), CAPLEK01 (Ymé n, 1983), CAPLEK02 (Yamin et al, 1996), CAPLEK03 (Bai et al, 2010), RISNEN (Quan et al, 2008), ULOXIC (Bodige & Watson, 2003), PIPTHS (Dix & Rae, 1973), PIPTHS01 (Shi & Wang, 1992), EWESUW (Nath et al, 2016), BOMPAU (Rout et al, 1982), VOHFIH (Polyakova & Starikova, 1990), VOHFIH01 (Ivanov et al, 2003), PECWOL…”