A pyridine adduct of bis(di-iso-butyldithiocarbamato-S,S′)cadmium(II): Multinuclear (13C, 15N, 113Cd) CP/MAS NMR spectroscopy, crystal and molecular structure, and thermal behaviour

Dithiocarbamates Strongly Inhibit Carbonic Anhydrases and Show Antiglaucoma Action in Vivo

“…We prepared a series of 27 DTCs, of types 1a – 27a , by the classical reaction ,, of dithiocarbamoylation between primary/secondary amines 1 – 27 and CS 2 , in the presence of a base, which most of the time was NaOH, KOH, but in the case of more basic amines, the amine itself can act as the base (Scheme ). As shown in Table , a large variety of R 1 and R 2 moieties are present in DTCs reported here, that is, hydrogen, alkyl, aryl, aralkyl, hetaryl, and cyclic such moieties, which lead to the generation of a wide chemical diversity in these compounds.…”

A two-dimensional coordination polymer: poly[[bis[μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3N:S,S′]cadmium(II)] 3-methylpyridine monosolvate]

“…The addition of monodentate pyridyl-N donor molecules during adduct formation more often than not results in the breakdown of the binuclear motif to form a mononuclear species, e.g. as in the structures of Cd{S 2 CN[CH 2 C(H)Me 2 ] 2 } 2 (pyridine) (Rodina et al, 2011) and Cd[S 2 CN(Me)Ph] 2 (pyridine) 2 (Onwudiwe et al, 2013). The latter structure shows it is possible for the Cd II atom to increase its coordination number to six in the presence of N-donors.…”

LASER-INDUCED MODIFICATION ON SOME PROPERTIES OF PREPARED Cu(II) COMPLEXES

“…Also, the importance of the Cu complex currently lies in the fact that Cu may be used to cancer treatment [2]. Dithiocarbamate ligands coordinating through sulfur atoms with transition metals, dithiocarbamate complexes can present an extreme range of applications in chemistry, agriculture, medicine, and others [3,4]. The complexes with square planar shape of Ni(II) and Cu(II) with potassium-based dithiocarbamate are directly prepared [5].…”