The effect of suspended inert solid particles on gas-liquid mass transfer has been investigated in the vessels equipped with standard and modi®ed Rushton turbine agitators positioned singly or doubly on same shaft.The relations between the volumetric mass transfer coef®cient in various suspensions, speci®c power consumption and super®cial gas velocity were obtained.Mixing with the modi®ed Rushton turbines having the surface fraction of the perforations equal to 0.353, the oxygen transfer ef®ciency is over 45% higher than that obtained using standard Rushton turbines.
List of symbolsoxygen transfer ef®ciency (m 3 O 2 /Wh) K consistency index (Pas n ) k L a volumetric mass transfer coef®cient (s A1 ) n¯ow behavior index (A) n p number of blades of mixing system (A) N agitator speed (s A1 ) P g power consumption in gas-liquid system (W) P gs power consumption in gas-liquid-solid system (W) r coef®cient of correlation (A) S1, S3 particle types (A) S C full surface of the blade (m 2 ) S G surface of the perforations applied on the blade (m 2 ) S G aS C surface fraction of the perforations (A) 1TP3, 2TP3 modi®ed blade turbines, single and double respectively (A) 1TR, 2TR standard Rushton turbines, single and double respectively (A) v s super®cial gas velocity (m/s) V L , V S volume of the liquid and suspension respectively (m 3 ) X particle concentration (g/l) w baf¯e width (m)
IntroductionIn multiphase processes carried out in stirred vessels, interphase mass transfer is often an important step and may be rate determining for the overall process. The k L a values in mechanically agitated reactors depend on various parameters like system properties, vessel and stirrer dimensions and arrangement and operating conditions [1].For slurry reactors, it has been observed that the addition of solids has an in¯uence on gas-liquid mass transfer characteristics, even if these particles are not reactive and do not show increased adsorption of dissolved gases [2±4].In the systems with inert particles, k L a increases slightly at low particle concentrations under otherwise constant conditions but drops sharply if the viscosity of the slurry system relative to the liquid exceeds a value of roughly 4 [1±4].In the work [5], the gas-liquid mass transfer in a sparged vessel agitated by one, respectively two standard and modi®ed Rushton turbine agitators, was characterized.Between the ®ve modi®ed blade turbine types investigated, having a surface fraction S G aS C of the perforations in the range 0.117±0.588, the modi®ed turbine for which S G aS C is equal to 0.353 (noted TP3) was considered as optimum.The mass transfer ef®ciency of the TP3 modi®ed turbines, single or double, is over 30% higher than that obtained using the TR standard turbines.The purpose of this work is to examine the effect of the solid particles on gas-liquid mass transfer and to check the applicability of k L a correlations developed for gas-liquid systems.The TP3 modi®ed turbines, single or double, are compared with the standard turbines.The inert particles used are ...