RT), precluding the use of these materials to practical implementations. [2][3][4][5]14] The ferromagnetic state in magnetic metaldoped oxides and nitrides is available at RT but is localized to aggregated metal oxide/nitride nanoparticles without a longrange magnetic order. [4] The ferromagnetic state in van der Waals 2D materials has been observed recently in the monolayer limit. [15][16][17][18][19][20][21] Intrinsic CrI 3 and CrGeTe 3 semiconductors reveal ferromagnetism but the T c is still low below 60 K. [20,21] In contrast, monolayer VSe 2 and MnSe 2 are ferromagnetic metals with T c above RT but incapable of controlling its carrier density. [22,23] Moreover, the long-range ferromagnetic order in doped diluted chalcogenide semiconductors has not been demonstrated at RT. [24][25][26][27][28] The key research target is to realize the long-range order ferromagnetism, T c over RT, and semiconductor with gate tunability. Here, we unambiguously observe tunable magnetic domains by a gate bias above RT in diluted V-doped WSe 2 , while maintaining the semiconducting characteristic of WSe 2 with a high on/off current ratio of five orders of magnitude. Figure 1a illustrates the schematic for the synthesis of V-doped monolayer WSe 2 via chemical vapor deposition (CVD). A metal precursor solution prepared by mixing V and W liquid sources at a given atomic ratio was spin-coated on SiO 2 substrate and the substrate was introduced into the CVD chamber with selenium. The metal precursors get decomposed into metal oxides at growth temperature, resulting in monolayer V x W 1−x Se 2 , followed by selenization. The atomic ratio of V to W sources in precursor solution can be precisely controlled from 0.1% to 40%, while the hexagonal flakes are retained in a monolayer form (the optical image in Figure 1a; Figure S1, Supporting Information). Meanwhile, the dendritic and multilayer flakes are partially generated at higher V-concentration. The V atoms are incorporated into monolayer WSe 2 with V/W contents similar to nominal values, as confirmed by X-ray photoelectron spectroscopy ( Figure S2, Supporting Information). With low V-doping concentration, the hexagonal V-doped WSe 2 flake is a single crystal confirmed by previous TEM study. [29] To study the doping effect of vanadium to the electronic properties of WSe 2 , field effect transistors (FETs) of V-doped mono layer WSe 2 were fabricated (Figure 1b). The CVD-grown pristine WSe 2 manifests a p-type semiconductor with a threshold voltage at −50 V. The threshold voltage is shifted to −10 V for Diluted magnetic semiconductors including Mn-doped GaAs are attractive for gate-controlled spintronics but Curie transition at room temperature with longrange ferromagnetic order is still debatable to date. Here, the room-temperature ferromagnetic domains with long-range order in semiconducting V-doped WSe 2 monolayer synthesized by chemical vapor deposition are reported. Ferromagnetic order is manifested using magnetic force microscopy up to 360 K, while retaining high on/off current rati...