From rosin to high adhesive polyurethane acrylate: Synthesis and properties

Liu, Baihua; Nie, Jun; He, Yong

doi:10.1016/j.ijadhadh.2016.01.002

Cited by 30 publications

(13 citation statements)

References 31 publications

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“…Liu et at. [ 89 ] developed a polyurethane acrylate system with hydrogenated rosin. The Tg was 54.4 °C, and the positive effect of the rosin resulted in less shrinkage than that of a commercial oligomer, and a better adhesion to glass.…”

Section: Uv-curable Monomers From the Pulp And Paper Industrymentioning

confidence: 99%

UV-Curable Bio-Based Polymers Derived from Industrial Pulp and Paper Processes

et al. 2021

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Bio-based monomers represent the future market for polymer chemistry, since the political economics of different states promote green ventures toward more sustainable materials and processes. Industrial pulp and paper processing represent a large market that could advance the use of by-products to avoid waste production and reduce pollution. Lignin represents the most available side product that can be used to produce a bio-based monomer. This review is concentrated on the possibility of using bio-based monomer derivates from pulp and the paper industry for UV-curing processing. UV-curing represents the new frontier for thermoset production, allowing a fast reaction cure, less energy demand, and the elimination of solvent. The growing demand for new monomers increases research in the environmental field to substitute for petroleum-based products. This review provides an overview of the main monomers and relative families of compounds derived from industrial processes that are suitable for UV-curing. Particular focus is given to the developments reached in the last few years concerning lignin, rosin and terpenes and the related possible applications of these in UV-curing chemistry.

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Section: Uv-curable Monomers From the Pulp And Paper Industrymentioning

confidence: 99%

UV-Curable Bio-Based Polymers Derived from Industrial Pulp and Paper Processes

et al. 2021

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“…The RA presence increased the decomposition temperature in polymeric monodisperic materials [ 51 ]. Hydrogenated rosin used in high adhesion polyurethane acrylate improved the adhesion ability and decreased volume shrinkage during radical UV-curing polymerization process which is a problem with linear analogues [ 52 ].…”

Section: The Use Of Tall Oilmentioning

confidence: 99%

A Review of Wood Biomass-Based Fatty Acids and Rosin Acids Use in Polymeric Materials

et al. 2020

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In recent decades, vegetable oils as a potential replacement for petrochemical materials have been extensively studied. Tall oil (crude tall oil, distilled tall oil, tall oil fatty acids, and rosin acids) is a good source to be turned into polymeric materials. Unlike vegetable oils, tall oil is considered as lignocellulosic plant biomass waste and is considered to be the second-generation raw material, thus it is not competing with the food and feed chain. The main purpose of this review article is to identify in what kind of polymeric materials wood biomass-based fatty acids and rosin acids have been applied and their impact on the properties.

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“…Rosin-based high adhesion polyurethane acrylate is a faint-yellow solid. It can be synthesized from hydrogenated rosin, isophorone diisocyanate and 2-hydroxyethyl acrylate according to Scheme 14, prior to precipitation, vacuum drying and column chromatography [173]. Its application is an adhesive having a high polymerization rate, low volume shrinkage and high adhesion [173].…”

Section: Rosin-based Chemicalsmentioning

confidence: 99%

“…This catalyst is more efficient than others [208,209] Its applications include oxidation-resistant solvent-borne tackifiers and coatings, a substrate for esterification with glycerol [210], additives for polyvinylidene difluoride binders for lithium titanium oxide anodes [76]. It can be used in high-performance liquid epoxy resins [83], for synthesis of high adhesion polyurethane acrylate [173]. It is noteworthy, that non-catalytic decarboxylation of rosin can take place at temperatures above 200 °C, and the main product of such decomposition is norabieta-8,11,13-triene [211].…”

Section: Rosin-based Chemicalsmentioning

confidence: 99%

Advances in Rosin-Based Chemicals: The Latest Recipes, Applications and Future Trends

et al. 2019

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A comprehensive review of the publications about rosin-based chemicals has been compiled. Rosin, or colophony, is a natural, abundant, cheap and non-toxic raw material which can be easily modified to obtain numerous useful products, which makes it an excellent subject of innovative research, attracting growing interest in recent years. The last extensive review in this research area was published in 2008, so the current article contains the most promising, repeatable achievements in synthesis of rosin-derived chemicals, published in scientific literature from 2008 to 2018. The first part of the review includes low/medium molecule weight compounds: Especially intermediates, resins, monomers, curing agents, surfactants, medications and biocides. The second part is about macromolecules: mainly elastomers, polymers for biomedical applications, coatings, adhesives, surfactants, sorbents, organosilicons and polysaccharides. In conclusion, a critical evaluation of the publications in terms of data completeness has been carried out with an indication of the most promising directions of rosin-based chemicals development.

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From rosin to high adhesive polyurethane acrylate: Synthesis and properties

Cited by 30 publications

References 31 publications

UV-Curable Bio-Based Polymers Derived from Industrial Pulp and Paper Processes

UV-Curable Bio-Based Polymers Derived from Industrial Pulp and Paper Processes

A Review of Wood Biomass-Based Fatty Acids and Rosin Acids Use in Polymeric Materials

Advances in Rosin-Based Chemicals: The Latest Recipes, Applications and Future Trends

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