In this work, the layer-by-layer self-assembly technology was used to modify aramid fibers (AFs) to improve the interfacial adhesion to epoxy matrix. By virtue of the facile layer-by-layer self-assembly technique, poly(l-3,4-Dihydroxyphenylalanine) (l-PDOPA) was successfully coated on the surface of AFs, leading to the formation of AFs with controllable layers (nL-AF). Then, a hydroxyl functionalized silane coupling agent (KH550) was grafted on the surface of l-PDOPA coated AFs. The properties such as microstructure and surface morphology of AFs before and after modification were characterized by FTIR, XPS and FE-SEM. The results confirmed that l-PDOPA and KH550 were successfully introduced into the surface of AFs by electrostatic adsorption. The interfacial properties of AFs reinforced epoxy resin composites before and after coating were characterized by interfacial shear strength (IFSS), interlaminar shear strength (ILSS) and FE-SEM, and the results show that the interfacial adhesion properties of the modified fiber/epoxy resin composites were greatly improved.
Urbanization is accelerating due to economic and societal development. The accurate identification of urban functional zones is significant for urban structure optimization, urban planning, and resource allocation. This paper reviews the scholarly literature on urban functional zone identification. Based on the retrieval results of databases, we analyzed the overview and current status. The identification methods and classification schemes are summarized from the existing research. The following results were obtained: (1) point of interest (POI) data are widely used for functional zone identification; (2) the block is the most common unit for functional zone identification; (3) cluster analysis is the main approach for urban functional zone identification; (4) most of the classification schemes are based on the dominant land use and characteristics of data sources. We predict future trends of urban functional zone identification based on the reviewed literature. Our findings are expected to be valuable for urban studies.
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