From ethyl biodiesel to biolubricants: Options for an Indian mustard integrated biorefinery toward a green and circular economy

Chen, Jing; Bian, Xiaoqiang; Rapp, Graeme; Lang, James; Montoya, Alejandro; Trethowan, Richard; Bouyssière, Brice; Portha, Jean-François; Jaubert, Jean‐Noël; Pratt, Peter; Coniglio, Lucie

doi:10.1016/j.indcrop.2019.04.041

Cited by 33 publications

(21 citation statements)

References 45 publications

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“…Catalysts 2020, 10, x FOR PEER REVIEW 2 of 12 consequently, a key for the development of local economies [5][6][7][8]. Indeed, they have been used as raw materials for biolubricant production from different ways [1,9,10].…”

Section: Raw Materials Characterizationmentioning

confidence: 99%

“…Moreover, the fatty acid component of biolubricants can form layers and a stable film on the surfaces of rubbing zones, avoiding the contact between surfaces and therefore, corrosion and wear [4]. Many raw materials (such as rapeseed or castor) could contribute to the sustainable development, being an alternative to rotate typical crops in many regions and being an alternative to petroleum fuels or products and, consequently, a key for the development of local economies [5][6][7][8]. Indeed, they have been used as raw materials for biolubricant production from different ways [1,9,10].…”

Section: Introductionmentioning

confidence: 99%

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Biolubricants from Rapeseed and Castor Oil Transesterification by Using Titanium Isopropoxide as a Catalyst: Production and Characterization

et al. 2020

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The transesterification of rapeseed and castor oil methyl esters with different alcohols (2-ethyl-1-hexanol, 1-heptanol and 4-methyl-2-pentanol) and titanium isopropoxide as a catalyst, to produce biolubricants, was carried out. Parameters such as temperature, alcohol/methyl ester molar ratio, and catalyst concentration were studied to optimize the process. The reaction evolution was monitored with the decrease in FAME concentration by gas chromatography. In general, the reaction was almost complete in two hours, obtaining over 93% conversions. All the variables studied influenced on the reaction yields. Once the optimum conditions for the maximum conversion and minimum costs were selected, a characterization of the biolubricants obtained, along with the study of the influence of the kind of alcohol used, was carried out. The biolubricants had some properties that were better than mineral lubricants (flash points between 222 and 271 °C), needing the use of additives when they do not comply with the standards (low viscosity for rapeseed biolubricant, for instance). There was a clear influence of fatty acids of raw materials (oleic and ricinoleic acids as majority fatty acids in rapeseed and castor oil, respectively) and the structure of the alcohol used on the final features of the biolubricants.

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Section: Raw Materials Characterizationmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Biolubricants from Rapeseed and Castor Oil Transesterification by Using Titanium Isopropoxide as a Catalyst: Production and Characterization

et al. 2020

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“…Biomass harnessing in accordance with the biorefinery and green circular economy concepts to generate energy carriers and high valueadded products from conversion technologies satisfying the eco-design, eco-energy and eco-materials criteria is an essential environmental, economic and social issue [1,2]. Production of biodiesel and biolubricants from non-edible oilseed plants by reactive distillation using transesterification as conversion route is such an illustration [2,3]. Indeed, first, this class of biomass does not bring about indirect land use change and even often contributes to soil improvement (erosion prevention or biofumigation).…”

Section: Introductionmentioning

confidence: 99%

Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production

Roze

Pignat

Ferreira

et al. 2021

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The aim of this paper is to bring valuable phase equilibria information for the design and operation of biolubricant and related biofuel product processes. As a result, Vapor-Liquid Equilibrium (VLE) measurements, at different temperatures, pressures and global compositions, for the ternary systems [Ethanol + 2-Ethyl-1-hexanol + 1-Dodecanol] and [Ethanol + 1-Octanol + 1-Dodecanol], as well as a multicomponent system containing these alcohols together with Balanites aegyptiaca fatty acid ethyl esters are reported for the first time (data pressure and temperature ranges: 4394-26790 Pa, 306-423 K). The Dortmund modified UNIFAC model showed very high accuracy in the prediction of these VLE, with overall average absolute deviations on the liquid and vapor molar compositions of 0.007 and 0.0003 for the ternary systems, 0.003 and 0.006 for the multicomponent system.

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“…The oil obtained from the seeds of rapeseed and mustard has a unique biochemical composition and is used not only for food purposes, but also as a biological fuel. The seed meal of these crops is a source of fodder for farm animals, because it contains a large amount of protein [1][2][3]. It is balanced in amino acid composition, contains a large amount of fat, available nitrogen, and phosphorus.…”

Section: Introductionmentioning

confidence: 99%

The evaluation of parental material of winter rapeseed (Brassica napusL.) and winter brown mustard (Brassica junceaL.) on resistance to Phoma rot in the central zone of the Krasnodar region of the Russian Federation

2020

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In 2018-2020, Phoma rot (Leptosphaeria maculans Ces. & De Not) in the form of stem canker was the most common disease on winter rapeseed and winter brown mustard in the central zone of the Krasnodar region of the Russian Federation. Given the high prevalence and development of the disease in all years of research, we identified the rapeseed samples resistant to it; they had the affection degree of 1-2 points (9.0-12.0% of the total number of studied samples). The rest of the samples were weakly resistant with the affection degree of 3-4 points (33.0-39.0 % of samples), weakly susceptible with the affection degree of 5-6 points (28.0-40.0 % of samples) and susceptible with the affection degree of 7-9 points (15 0-23.0 % of samples). We also identified the samples resistant to Phoma rot during the examination of mustard. Their number was lower than that of the rapeseed – 3.0-6.0 % of the total number of samples. The main part of the samples was weakly resistant with the affection degree of 3-4 points (47.0-63.0 % of the total number of samples). The rest of the samples during the years of research were weakly susceptible with the affection degree of 5-6 points (11.0-30.0 %) and susceptible (9.0-18.0 %). The parental material of winter rapeseed and winter brown mustard, resistant to disease, can be used as the donors of resistance to Phoma rot in breeding work during the development of the new promising varieties.

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From ethyl biodiesel to biolubricants: Options for an Indian mustard integrated biorefinery toward a green and circular economy

Cited by 33 publications

References 45 publications

Biolubricants from Rapeseed and Castor Oil Transesterification by Using Titanium Isopropoxide as a Catalyst: Production and Characterization

Biolubricants from Rapeseed and Castor Oil Transesterification by Using Titanium Isopropoxide as a Catalyst: Production and Characterization

Phase equilibria of mixtures involving fatty acid ethyl esters and fat alcohols between 4 and 27 kPa for bioproduct production

The evaluation of parental material of winter rapeseed (Brassica napusL.) and winter brown mustard (Brassica junceaL.) on resistance to Phoma rot in the central zone of the Krasnodar region of the Russian Federation

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