In the Penning trap, there is transport of electrons in the limit of zero gas pressure that arises from asymmetric stray electric fields. In an annular version of the Penning trap, this asymmetry transport is shown to be greatly reduced when the plasma-facing surfaces are coated with colloidal graphite. In a separate device, an emissive probe is used to examine the space potential a few millimeters above coated and uncoated surfaces. It is found that the rms potential variation is approximately 250 mV for uncoated surfaces and 15 mV for coated surfaces. The characteristic length scale of the inhomogeneities is ∼1 cm. Glow-discharge cleaning, which is easily renewed, is shown to reduce the potential variation to the same level that is obtained with the colloidal graphite coating.