Formation of clathrate hydrates under crystallization of gas-saturated amorphous ice

Faĭzullin, M. Z.; Vinogradov, A. P.; Koverda, V. P.

doi:10.1016/j.ijheatmasstransfer.2013.06.023

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Methane Storage1

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Cited by 22 publications

(2 citation statements)

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“…Indirect methane hydrate formation can start from ice and could result in a high yield. However, this approach may not be economic due to the high energy spending and longer time associated with the ice formation [107].…”

Section: Methane Storagementioning

confidence: 99%

Zeolitic ice: A route toward net zero emissions

Omran

Nesterenko

Valtchev

2022

Renewable and Sustainable Energy Reviews

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Section: Methane Storagementioning

confidence: 99%

Zeolitic ice: A route toward net zero emissions

Omran

Nesterenko

Valtchev

2022

Renewable and Sustainable Energy Reviews

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“…A lot of contributions are dedicated to the enhancement of the hydrate formation process. A great deal of articles are devoted to experimental and mathematical modeling of gas hydrates formation and decomposition processes38394041. There are many patents for hydrate formation methods and big corporations, such as Mitsui, Toyota, Chevron and others are their holders.…”

mentioning

confidence: 99%

New hydrate formation methods in a liquid-gas medium

Chernov

Pil’nik

Elistratov

et al. 2017

Sci Rep

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Conceptually new methods of hydrate formation are proposed. The first one is based on the shock wave impact on a water-bubble medium. It is shown that the hydrate formation rate in this process is typically very high. A gas hydrate of carbon dioxide was produced. The process was experimentally studied using various initial conditions, as well as different external action magnitudes. The obtained experimental data are in good agreement with the proposed model. Other methods are based on the process of boiling liquefied gas in an enclosed volume of water (explosive boiling of a hydrating agent and the organization of cyclic boiling-condensation process). The key features of the methods are the high hydrate formation rate combined with a comparatively low power consumption leading to a great expected efficiency of the technologies based on them. The set of experiments was carried out. Gas hydrates of refrigerant R134a, carbon dioxide and propane were produced. The investigation of decomposition of a generated gas hydrate sample was made. The criteria of intensification of the hydrate formation process are formulated.

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