“…MHC typically precipitates with other carbonates such as Mg-calcite, aragonite, Ca-rich dolomite, hydromagnesite and nesquehonite under conditions of calcite inhibition (Broughton, 1972;Fischbeck and Müller, 1971;Nishiyama et al, 2013;Rodriguez-Blanco et al, 2014;Taylor, 1975;Warthmann et al, 2000). The increase in TA and pH during sulfate reduction with formate, conditions which are known to favor carbonate precipitation (Braissant et al, 2003;Davies et al, 1977;Ganendra et al, 2014;Hammes and Verstraete, 2002;Meister, 2013;Taylor, 1975;Warthmann et al, 2000), likely favored MHC formation in the medium. The importance of the TA increase to MHC formation was evident since the mineral did not form during sulfate reduction with hydrogen in acetate medium which produced in a similar increase in pH without an accompanying increase in TA.…”