Flow Injection Chemiluminescence Determination of Amino Acids by Oxidation with N-Bromosuccinimide

Guang-hong, Zhou; Chen, Hong‐Yuan

doi:10.2116/analsci.18.693

Cited by 17 publications

(10 citation statements)

References 29 publications

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“…Previous studies have shown that fluorescein accepted the energy generated from a redox reaction of NBS with analyte molecules, and was excited to produce CL (32)(33)(34)(35)(36). Previous studies have shown that fluorescein accepted the energy generated from a redox reaction of NBS with analyte molecules, and was excited to produce CL (32)(33)(34)(35)(36).…”

Section: Possible Mechanism Of CL Reactionmentioning

confidence: 99%

Flow‐injection chemiluminescence determination of diazepam by oxidation with N‐bromosuccinimide

2012

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A rapid and sensitive flow-injection chemiluminescence (FI-CL) method is described for the determination of diazepam based on its reaction with N-bromosuccinimide (NBS) in alkaline medium in the presence of dichlorofluorescein (DCF) as an effective energy-transfer agent. Under optimum conditions, the proposed method allowed the measurement of diazepam over the range of 2.0 × 10(-6) to 2.0 × 10(-4) mol/L with a detection limit of 5.0 × 10(-7) mol/L. The relative standard deviation for 11 parallel measurements of 2.0 × 10(-5) mol/L diazepam was 2.1%. The method was applied satisfactorily for the determination of diazepam in pharmaceutical preparations, and the results agree well with those obtained by spectrophotometry. The use of the proposed system for the determination of diazepam in urine and plasma samples was also tested. The possible mechanism of the chemiluminescence reaction is discussed briefly.

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Section: Possible Mechanism Of CL Reactionmentioning

confidence: 99%

Flow‐injection chemiluminescence determination of diazepam by oxidation with N‐bromosuccinimide

2012

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“…Detection methods for glycine include precolumn derivatization [3,4], HPLC chromatography [5][6][7], chemiluminescene [8,9], fluorimetriic methods [10,11] and capillary electrophoresis [12,13]. 1 This work was supported by National Natural Science Foundation of China (Grant No.…”

Section: Introductionmentioning

confidence: 99%

A molecule-imprinted polyaniline membrane modified on carbon fiber for detection of glycine

Zeng

Wang

2014

Bio-Medical Materials and Engineering

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A layer of L-glycine-molecule-imprinted polyaniline (LMIP-PANI) polymer film has been modified on a carbon fiber electrode for the determination of L-glycine standard samples and L-glycine in cerebrospinal fluid of wistar mice. It has been found that a linear relationship exists between current and concentration for the glycine standard samples in the range of 0-12 μM by using the LMIP-PANI-modified carbon fiber electrode as a sensor. However, there is no any relationship between current and concentration for the carbon fiber electrode modified with no-glycine-molecule-imprinted polyaniline (NIP-PANI). The MIP-PANI-and NIP-PANI-modified carbon fiber films have been characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and electrochemistry methods. The investigation shows that the MIP-PANI-imprinted carbon fiber electrode will have a potential application in in-situ monitoring neurotransmitter due to its easy fabrication, low cost, bio-compatibility and flexibility.

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“…Over the past few years, several analytical methods have been developed to quantify L-PA including high performance liquid chromatography with fluorescence detection (Kand'ar & Žáková, 2009;Wróbel & Wróbel, 1997), capillary electrophoresis (Mohammad, Fujinari, Okorodudu, & Petersen, 2000;Tagliaro et al, 1994), spectrophotometry (Parra, Mateos, Mata, & de Marí a, 1998), enzymatic method (Bazukyan, Hambardzumyan, Andreasyan, & Popov, 2008;Hummel, Schütte, & Kula, 1988), potentiometry and colorimetry (Pijanowska & Remiszewska, 2006), electrochemical method (Hu, Zhang, Zhang, Luo, & Yao, 2011), and flow-injection (Costin, Francis, & Lewis, 2003;Hanaoka, Lin, & Yamada, 2000;Hara, Toriyama, Ebuchi, & Imaki, 1985;MacDonald & Nieman, 1985;Zhou & Chen, 2002). Most of the above-mentioned methods have suffered from various drawbacks including poor sensitivity, poor detection limits, sample separation, and expensive instrumentation.…”

Section: Introductionmentioning

confidence: 99%

Microfluidic chip based chemiluminescence detection of L-phenylalanine in pharmaceutical and soft drinks

et al. 2012

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Flow Injection Chemiluminescence Determination of Amino Acids by Oxidation with N-Bromosuccinimide

Cited by 17 publications

References 29 publications

Flow‐injection chemiluminescence determination of diazepam by oxidation with N‐bromosuccinimide

Flow‐injection chemiluminescence determination of diazepam by oxidation with N‐bromosuccinimide

A molecule-imprinted polyaniline membrane modified on carbon fiber for detection of glycine

Microfluidic chip based chemiluminescence detection of L-phenylalanine in pharmaceutical and soft drinks

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