1987
DOI: 10.1055/s-2006-962766
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Flavonoidglycoside ausArnica montanaundArnica chamissonis1

Abstract: Five flavonoid glycosides were identified from flowers of ARNICA MONTANA, four from A. CHAMISSONIS subsp. FOLIOSA var. INCANA. The structures were established on the basis of total acid hydrolysis and spectral data (UV, (1)H-NMR, (13)C-NMR, MS) as hispidulin 7- O-beta-glucoside, isorhamnetin 3- O-beta-glucoside, 3- O-beta- D-glucopyranosides of spinacetin, 6-methoxykaempferol and patuletin and querectin 3- O-(6''- O-acetyl)-beta- D-glucopyranoside. The latter compound can serve as distinctive marker between th… Show more

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Cited by 61 publications
(41 citation statements)
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“…Acetates are common, but other aliphatic acids are encountered, malonic and succinic for example. Singly acetylated flavone or flavonol glycosides have been reported from Arnica (Merfort, 1986(Merfort, , 1988aMerfort and Wendisch, 1987), Chrysactinia (Harborne et aI., 1991), Chrysanthemum (Hu et aI., 1994), Doronicum (Reynaud et aI., 1985;Reynaud and Raynaud, 1986), Helenium and Plummera (Wagner et aI., 197Ic), Hymenoxys (Wagner et aI., 1972h), Matricaria (Kunde andIsaac, 1979; Redaelli et aI., 1980; Pietta et aI., 1987) and Senecio (Piegay et aI., 1986). Chalcones and aurones have also been found to occur as acetylated glycosides in a few species.…”
mentioning
confidence: 99%
“…Acetates are common, but other aliphatic acids are encountered, malonic and succinic for example. Singly acetylated flavone or flavonol glycosides have been reported from Arnica (Merfort, 1986(Merfort, , 1988aMerfort and Wendisch, 1987), Chrysactinia (Harborne et aI., 1991), Chrysanthemum (Hu et aI., 1994), Doronicum (Reynaud et aI., 1985;Reynaud and Raynaud, 1986), Helenium and Plummera (Wagner et aI., 197Ic), Hymenoxys (Wagner et aI., 1972h), Matricaria (Kunde andIsaac, 1979; Redaelli et aI., 1980; Pietta et aI., 1987) and Senecio (Piegay et aI., 1986). Chalcones and aurones have also been found to occur as acetylated glycosides in a few species.…”
mentioning
confidence: 99%
“…(Lyss et al, 1997, Wagner et al, 2004Merfort, 2003;Wagner i Merfort, 2007). Pored sekviterpenskih laktona najviše izučavana jedinjenja u cvetu arnike su svakako flavonoidi u formama flavonoidnih glikozida (Merfort i Wendisch 1987, flavonoidnih glukunorida (Merfort i Wendisch 1988) i flavonoidnih aglikona (Merfort i Wendisch 1985). Ostale prateće supstance u cvetu arnike su karotenoidi (Vanhaelen, 1973), diterpeni (Schmidt et al, 1992); arnidiol (triterpen) (Santer i Stevenson, 1962), pirolizidinski alkaloidi (tusilagin i izotusilagin) , poliacetileni (Schulte et al, 1969), kumarini (umbeliferon i skopoletin) (Willuhn, 1989), fenolne kiseline (holorogenska kiselina, kafena kiselina i cinarin) (Merfort, 1992;Ebert et al, 1988;Kohlmünzer 2000;Reyes-Salas et al 2002), lignani (Schmidt et al 2006) and oligosaharidi (White et al, 1985;Kennedy et al, 1988).…”
Section: Hemijska Identifikacijaunclassified
“…Fenolna jedinjenja su identifikovana poređenjem sa autentičnim referentnim jedinjenjima izolovanim iz arnike u prehodnim studijama (Merfort, 1984;Merfort i Wendisch, 1987;Spitaler et al, 2006) (Tabela 28). Od identifikovanih jedinjenja za određivanje sadržaja odabrana je jedna fenolna kiselina (hlorogenska kiselina) i dva dominantna flavonoida (kvercetin-3-O-glukozid i kempferol-3-O-glukozid).…”
Section: Sadržaj Dominantnih Fenolnih Komponentiunclassified
“…Its other constituents are triterpene arnidiol, flavonoids, coumarins, tannins, pyrrolizidine alkaloids, essential oil, etc (ESCOP 2000, Kos et al 2005, Merfort 1992, Merfort and Wendisch 1987, Murav'eva, Samylina, and Yakovlev 2002, Yakovlev and Blinova 1999, 2004. The dried rhizome and roots of mountain arnica are also used, although seldom; their constituents are similar to those of the flowers (Evans 2000).…”
Section: Arnica Montanamentioning
confidence: 99%