2002
DOI: 10.1590/s0103-50532002000500021
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Fatty Acid Esters of Triterpenes from Erythroxylum passerinum

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Cited by 42 publications
(20 citation statements)
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“…As a result, it was also suggested that the compound described as 11a-hydroxy-b-amyrin, isolated from Stauntonia hexaphylla callus (Ikuta and Morikawa, 1992) must also be a 11b-hydroxy derivative, since its C-11 carbon (Yuan et al, 1994). Therefore, the 11-hydroxy-b-amyrin fatty acid ester isolated from Erythroxylum passerinum (Barreiros et al, 2002) must be the 11a-hydroxy derivative instead of the 11b-epimer, as deduced by comparison with the compound isolated by Ikuta and Morikawa (1992). However, the above conclusion seems to be in disagreement with the large J 9,11 value (9.4 Hz) for the reported 11b-derivatives from P. kleinii (Lima et al, 2005), although, this fact could have an explanation if the dihedral angle between H-11 and H-9 has values close to 0°i n the C-11b-hydroxy derivatives.…”
Section: Resultsmentioning
confidence: 99%
“…As a result, it was also suggested that the compound described as 11a-hydroxy-b-amyrin, isolated from Stauntonia hexaphylla callus (Ikuta and Morikawa, 1992) must also be a 11b-hydroxy derivative, since its C-11 carbon (Yuan et al, 1994). Therefore, the 11-hydroxy-b-amyrin fatty acid ester isolated from Erythroxylum passerinum (Barreiros et al, 2002) must be the 11a-hydroxy derivative instead of the 11b-epimer, as deduced by comparison with the compound isolated by Ikuta and Morikawa (1992). However, the above conclusion seems to be in disagreement with the large J 9,11 value (9.4 Hz) for the reported 11b-derivatives from P. kleinii (Lima et al, 2005), although, this fact could have an explanation if the dihedral angle between H-11 and H-9 has values close to 0°i n the C-11b-hydroxy derivatives.…”
Section: Resultsmentioning
confidence: 99%
“…All the three most commonly consumed plants belong to families known to contain toxins. For example, several of the c. 250 species of the genus Erythroxylum investigated for chemical composition contained alkaloids and terpenes, especially triterpenes in the leaves and fruits (Zuanazzi et al, 2001;Barreiros et al, 2002). Triterpenes are also found in M. obtusifolia (Alves et al, 2000).…”
Section: Discussionmentioning
confidence: 99%
“…[16][17][18] Different partitionates i.e. petroleum ether (PESF), dichloromethane (DCMSF), chloroform (CSF) and aqueous soluble fractions (AQSF) were tested for brine shrimp lethality according to the procedure of Meyer et al 13 .…”
Section: β-Sitosterolmentioning
confidence: 99%