“…Its high electron mobility (up to 10 3 cm 2 V À1 s À1 at 300 K), 8 p-or n-type doping, 9 tunable band gap from the NIR (E g ¼ 1.26 eV at 300 K) to the visible (VIS) range, 10 as well as chemical stability in air, 11 represent attractive features for versatile band engineering and reliable devices for electronics and optoelectronics. Recent reports have demonstrated optical devices based on heterostructure stacks of InSe and other vdW crystals (e.g., GaSe, graphene, and CuInSe 2 ) 9,12,13 or oxides (e.g., CdO, and ZnO), 14,15 and p-n junctions based on surface functionalization of n-InSe. 16 Here, we report on a heterojunction that combines the NIR p-InSe with the MIR n-InAs.…”