The
catalytic activation of thermochemical fluids or binary mixtures
(BMs) based on ammonium nitrate and sodium nitrite was experimentally
and numerically investigated as well as kinetically modeled. Experimental
evidence in an autoclave reactor indicated an increase of temperature
up to 242.5 °C and pressure up to 47.7 bar after the catalytic
activation under standard conditions is accomplished. By means of
the T and P growth and the observed
reaction products (N2, NO2, and H2O), the reaction kinetic constants along with its stoichiometry were
established and later on validated with a numerical reactor model.
Subsequently, field-scale numerical models evaluated the activation
of the BM within different reservoir rock quality (porosity: 3–15%
and permeability: 4.4–111 mD), fluid type (light and heavy
oils), injection rate (1–3 m3), and initial reservoir
pressure (85 and 150 bar). Poor reservoir quality and injection rate
were observed as the dominant requirements to ensure a more aggressive
reservoir fracking. They illustrated an exponential response on the
peak pressure, particularly at porosity and permeability values <5%
and <17 mD, respectively. The exhibited peak pressures in our models
range from 108–389 to 144–392 bar, for the light and
heavy oils, respectively. We found that these in situ pressures are
substantially in excess in reference to the predicted fracking pressure
of the studied reservoirs. This implies that the activation of the
BM within the porous media is a promising reservoir fracking method.
Moreover, its robust exothermicity surpasses the reported glass transition
and melting temperature of certain asphaltenes. Our findings can provide
meaningful understanding about the geologyinjection requirements
that can lead to fracking a given reservoir as well as its thermal
development potential for well cleaning purposes when implementing
BM for IOR applications.