EPR studies of spin-crossover of the tris-(di-n-butyldithiocarbamato)Fe(III) chlorobenzene solvate

Gelerinter, Edward; Stefanov, Michael E.; Lockhart, Thurmon E.; Rininger, David P.; Duffy, Norman V.

doi:10.1016/0022-1902(80)80424-6

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Characterisation By Spectroscopic Techniques1

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“…The EPR spectra demonstrate two kinds of signals associated with the 6 A 1 and 2 T 2 states [51][52][53][54][55][56], albeit some controversy still exists concerning the reliability of some of these data. This is motivated by the difficulties encountered in, for instance, the preparation of a pure sample, the possibility of sample decomposition and in the definitive assignment of the EPR signals [51,55].…”

Section: Characterisation By Spectroscopic Techniquesmentioning

confidence: 99%

Iron(III) Spin Crossover Compounds

Koningsbruggen

Maeda

Oshio

2004

Topics in Current Chemistry

175

130

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In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio-b-diketonates and X-semicarbazones (X=S, Se). In addition, attention is directed to Fe(III) spin crossover systems of multidentate Schiff base-type ligands. Examples of spin inter-conversion in Fe(III) compounds induced by light irradiation are given.

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