Emulsion photobioelectrochemistry: Bacteriorhodopsin phototransfer of protons through the water/lipid interface

Gugeshashvili, M.I.; Portnov, V.I.; Volkov, Alexander G.; Chekulaeva, L. N.; Markin, Vladislav S.

doi:10.1016/0302-4598(91)80019-y

Cited by 4 publications

(1 citation statement)

References 15 publications

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“…The interfacial adsorption of biological macromolecules brings exciting applications towards the field which are still not sufficiently studied. For instance, the accommodation of the transmembrane proton pumpbacteriorhodopsinwithin the lipid monolayer deposited at the liquidliquid interface allowed photoinduced proton transfer to the organic phase [54]. In addition to practical limitation related to protein denaturation [55,56], set of works published more than 20 years ago left out unfinished debate concerning the mechanism of the bacteriorhodopsin assisted proton transfer across liquidliquid interface [55].…”

Section: Molecular Assembliesmentioning

confidence: 99%

Decorating soft electrified interfaces: From molecular assemblies to nano-objects

Półtorak¹,

Gamero‐Quijano²,

Herzog³

et al. 2017

Applied Materials Today

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The interface formed between two immiscible electrolyte solutions (ITIES) constitutes a fantastic playground for the investigation of charge (under the form of either ion or electron) transfer processes. We have reviewed here the routes for the modification of such soft interfaces by an accurate electrochemical control. The three main strategies developed in the past four decades include (i) the electrochemically controlled assembly of molecules and nano-objects; (ii) the in-situ electrogeneration of nanomaterials and (iii) the use of ex-situ synthesised membranes. Applications of functionalized ITIES in the fields of redox catalysis and electroanalysis of modified soft interfaces are also discussed.

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