“…[1], as ␣ 3 0 and for a* ӷ 1. This is confirmed for a suspension of particles with a* ϭ 104, as shown in Fig.…”
Section: Electrophoretic Velocitymentioning
confidence: 99%
“…Sauer and Davis (1) found that the coal/clay suspension obtained from a lake formerly used to store the effluent from a coal-washing plant near Centralia, Washington, could be clarified electrophoretically using modest potentials and low power consumption. The colloidal contaminants were found to be negatively charged at the nearly neutral pH of the lake water, and the major cation in the surrounding electrolyte solution was sodium.…”
Section: Introductionmentioning
confidence: 99%
“…He analyzed the motion of a single sphere in a fluid of infinite extent with an unpolarized, infinitesimally thin double layer. His wellknown expression for electrophoretic mobility, U/E*, is U E* ϭ ⑀ r ⑀ 0 * , [1] in which U is the electrophoretic velocity, E* is the applied electric field, ⑀ r is the dielectric constant of the electrolyte solution, ⑀ 0 is the permittivity of free space, * is the zeta potential, and is the fluid viscosity. The thickness of the double layer, Ϫ1 , where is the Debye-Hückel parameter, is given by…”
Section: Introductionmentioning
confidence: 99%
“…Particle-particle interactions become increasingly significant as the number density of particles in a suspension in- 1 To whom correspondence should be addressed.…”
“…[1], as ␣ 3 0 and for a* ӷ 1. This is confirmed for a suspension of particles with a* ϭ 104, as shown in Fig.…”
Section: Electrophoretic Velocitymentioning
confidence: 99%
“…Sauer and Davis (1) found that the coal/clay suspension obtained from a lake formerly used to store the effluent from a coal-washing plant near Centralia, Washington, could be clarified electrophoretically using modest potentials and low power consumption. The colloidal contaminants were found to be negatively charged at the nearly neutral pH of the lake water, and the major cation in the surrounding electrolyte solution was sodium.…”
Section: Introductionmentioning
confidence: 99%
“…He analyzed the motion of a single sphere in a fluid of infinite extent with an unpolarized, infinitesimally thin double layer. His wellknown expression for electrophoretic mobility, U/E*, is U E* ϭ ⑀ r ⑀ 0 * , [1] in which U is the electrophoretic velocity, E* is the applied electric field, ⑀ r is the dielectric constant of the electrolyte solution, ⑀ 0 is the permittivity of free space, * is the zeta potential, and is the fluid viscosity. The thickness of the double layer, Ϫ1 , where is the Debye-Hückel parameter, is given by…”
Section: Introductionmentioning
confidence: 99%
“…Particle-particle interactions become increasingly significant as the number density of particles in a suspension in- 1 To whom correspondence should be addressed.…”
“…Several experimental approaches have been used to measure the settling velocities in the past. Traditionally, three methods have been employed to measure settling velocities [12][13][14][15]: (1) measuring fall velocity of the liquid-particle interface (valid only for highly concentrated suspension with well defined interface); (2) measuring change in number concentration of particles with time above a fixed plane (applicable for large, optically observable particles) and; (3) measuring an average settling velocity of a marked particle in presence of other particles in the bulk of suspension. The laser light scattering method used in this study is inherently non-intrusive and can be used for extremely dilute suspensions with volume fractions as low as 10 −5 .…”
The chromatographic performance with respect to the flow behavior and dispersion in fixed beds of nonporous and macroporous particles (having mean intraparticle pore diameters of 41, 105, and 232 nm) has been studied in capillary HPLC and electrochromatography. The existence of substantial electroosmotic intraparticle pore flow (perfusive electroosmosis) in columns packed with the macroporous particles was found to reduce stagnant mobile mass transfer resistance and decrease the global flow inhomogeneity over the column cross-section, leading to a significant improvement in column efficiency compared to capillary HPLC. The effect of electroosmotic perfusion on axial dispersion was shown to be sensitive to the mobile phase ionic strength and mean intraparticle pore diameter, thus, on an electrical double layer interaction within the particles. Complementary and consistent results were observed for the average electroosmotic flow through packed capillaries. It was found to depend on particle porosity and distinct contributions to the electrical double layer behavior within and between particles. Based on these data an optimum chromatographic performance in view of speed and efficiency can be achieved by straightforward adjustment of the electrolyte concentration and characteristic intraparticle pore size.
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