Ein neuer Zugang zu Komplexen mit gemischten Elementliganden der 15. und 16. Gruppe - die Bildung ungewöhnlicher Trichalkogenophosphonat-Liganden in Fe/Cr-Clustern

Scheer, Manfred; Umbarkar, Shubhangi B.; Chatterjee, Saurav; Trivedi, Rajiv; Mathur, Purva

doi:10.1002/1521-3757(20010119)113:2<399::aid-ange399>3.0.co;2-k

Angew. Chem.

2001

DOI: 10.1002/1521-3757(20010119)113:2<399::aid-ange399>3.0.co;2-k

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Ein neuer Zugang zu Komplexen mit gemischten Elementliganden der 15. und 16. Gruppe - die Bildung ungewöhnlicher Trichalkogenophosphonat-Liganden in Fe/Cr-Clustern

Manfred Scheer

Shubhangi B. Umbarkar

Saurav Chatterjee

et al.

Abstract: Trithiophosphonato‐ und Triselenophosphonato‐Liganden in gemischten Fe/Cr‐Clustern wurden bei der Reaktion von [Fe3(CO)9(μ3‐Y)2] (Y=S oder Se) mit [CpCr(CO)2(η3‐P3)] in Gegenwart von Trimethylaminoxid erhalten. Diese neuartige Herstellungsmethode führt zu Clustern, die erstmals P(S)S2 und P(Se)Se2 als Liganden in komplexierter Form enthalten (siehe Strukturformel).

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A Synthetic Approach to Novel Group 13/15 Element Complexes

Leiner

Scheer

2002

Organometallics

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The gallium chloro complex [GaCl{Fe(CO)2Cp}2] (Cp = η 5-C5H5) was reacted with KP(SiMe3)2 under special conditions to yield the complexes [{CpFe(CO)}2{μ-(CO)}[μ-Ga{CpFe(CO)2}]] (1) and [{CpFe(CO)2}GaP(SiMe3)]4 (2). Furthermore, [[{CpFe(CO)2}ClGa](μ-PPh2)2FeCpCO] (4) was obtained by the reaction of [GaCl{Fe(CO)2Cp}2] with LiPPh2. Complexes 1, 2, and 4 have been characterized spectroscopically and by X-ray structure analysis. Complex 2 represents an ideal Ga4P4-heterocubane, the first Ga-containing example of this structural type with organometallic substituted group 13 elements. In the solid state compound 4 possesses an almost planar GaPFeP four-membered ring, a novel structural motif in mixed group 13/15 chemistry.

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A Synthetic Approach to Novel Group 13/15 Element Complexes

Leiner

Scheer

2002

Organometallics

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Ein neuer Zugang zu Komplexen mit gemischten Elementliganden der 15. und 16. Gruppe - die Bildung ungewöhnlicher Trichalkogenophosphonat-Liganden in Fe/Cr-Clustern

Cited by 1 publication

References 16 publications

A Synthetic Approach to Novel Group 13/15 Element Complexes

A Synthetic Approach to Novel Group 13/15 Element Complexes

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