2017
DOI: 10.1186/s11671-017-1994-z
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Effects of Rapid Thermal Annealing and Different Oxidants on the Properties of LaxAlyO Nanolaminate Films Deposited by Atomic Layer Deposition

Abstract: A comparative study of different sequences of two metal precursors [trimethylaluminum (TMA) and Tris(isopropylcyclopentadienyl) lanthanum (La(iPrCp)3)] for atomic layer deposition (ALD) lanthanum aluminum oxide (LaxAlyO) films is carried out. The percentage compositions of C and N impurity of LaxAlyO films were investigated using in situ X-ray photoelectron spectroscopy (XPS). The effects of different oxidants on the physical and chemical properties and electrical characteristics of LaxAlyO films are studied b… Show more

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Cited by 4 publications
(2 citation statements)
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“…It can be explained by the fact that the impurity concentration and defects decrease due to the thermal annealing supplying enough thermal energy for the by-products residing and dangling bonds decomposition and re-composition, leading to the HfO 2 /Al 2 O 3 gate stack becoming a good gate dielectric insulator. [18,19] However, as shown in Figs. 2(c) and 2(d), the density of leakage spots in sample B increases significantly after annealing, which indicates that the 087701-2 conductive paths increase significantly.…”
Section: Resultsmentioning
confidence: 89%
“…It can be explained by the fact that the impurity concentration and defects decrease due to the thermal annealing supplying enough thermal energy for the by-products residing and dangling bonds decomposition and re-composition, leading to the HfO 2 /Al 2 O 3 gate stack becoming a good gate dielectric insulator. [18,19] However, as shown in Figs. 2(c) and 2(d), the density of leakage spots in sample B increases significantly after annealing, which indicates that the 087701-2 conductive paths increase significantly.…”
Section: Resultsmentioning
confidence: 89%
“…SCEs [28] are influenced by both the EOT and physical gate oxide thickness, so it is essential to pay attention to both parameters in order to decrease the gate's leakage to an acceptable level. Increased attention has been paid to La 2 O 3 gate dielectrics and much research has been carried out to examine their proper functioning [29][30][31][32]. The form thickness mainly determines the structural properties of La 2 O 3 and the annealing temperature has to be well controlled to ensure the stability of the La 2 O 3 layer [33,34].…”
Section: Introductionmentioning
confidence: 99%