Effect of polyborazine additive on thermolysis of polyphenylsilane and polyvinylsilane

Hong, Lan-Young; Cao, Feng; Kim, Dong-Jin; Woo, Hee‐Gweon; Kim, Bo-Hye; Cho, Myong-Shik; Li, Xiaodong; Kim, Dong‐Pyo

doi:10.1016/j.jorganchem.2003.08.018

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Cited by 5 publications

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“…As the 29 Si chemical shift is affected by not only the nearestneighbor atoms but also the next-nearest-neighbor atoms in the presence of B atom as adjacent atoms of N atom, which may have caused the observed peak broadening. Moreover, the SiÁ/N bonds formed by dehydrocoupling between polyvinylsilane (PVS) containing Á/SiH 3 or polyphenylsilane (PPS) and PBN were observed by liquid phase 29 Si-NMR [26]. IR absorption of Si Á/N (870 cm (1 ) was difficult to be distinguished due to overlapping with CH 3 (867 cm (1 redistribution of SiÁ/Si and Si Á/H bonds.…”

Section: Resultsmentioning

confidence: 99%