Recently,
silver nanowire-based transparent conductive films (AgNW-based
TCFs) with excellent comprehensive performance have aroused wide and
great interest. However, it is always difficult to simultaneously
improve the performances of TCFs in all aspects. In this work, by
introducing silica nanoparticles (SiO2-NPs) with a smaller
particle size, several properties of AgNW-based TCFs were optimized
successfully. The transmittance and conductivity were improved simultaneously,
and smaller particle size was proven to be more suitable to achieve
TCFs with excellent optoelectrical properties. Typically, an AgNW/SiO2-based TCF with a sheet resistance of 250 Ω/sq and transmittance
of 93.6% (including the poly (ethylene terephthalate) substrate, abbreviated
as PET) could be obtained by using SiO2-NPs with a size
of ∼21 nm, and this transmittance is even higher than that
of the bare PET (91.8%) substrate. We demonstrated that the layer
formed through self-assembly of SiO2-NPs can cut down the
light scattering on the AgNW surface through total reflection, thus
leading to a low haze of AgNW/SiO2-based TCFs. Very interestingly,
the SiO2-NPs conducted away most of the heat generated
during laser ablation, protecting the AgNWs from excessive melt and
PET from empyrosis, and thus ensuring the TCFs with high transmittance
and patterning accuracy. Besides, AgNW/SiO2-based TCFs
have smaller surface roughness, better flexibility, and adhesive force.
To the best of our knowledge, the comprehensive performance of the
AgNW/SiO2-based TCFs reaches the highest level among recently
reported novel TCFs.