The characteristics of primary carbides in a commercial-sized (one ton) electroslag remelting (ESR) ingot of AISI H13 steel were investigated. The interaction between the primary carbides and inclusions was also clarified. The results indicate that there are two types of primary carbides, V-rich and Mo-rich primary carbides, in the H13 ESR ingot. The quantity, the area fraction, and the size of the two primary carbides tend to decrease from the center of the H13 ESR ingot to the outer surface. Additionally, the V-rich primary carbide is obviously larger than the Mo-rich primary carbide. The Al 2 O 3 inclusion can promote the precipitation of the V-rich primary carbide, while the MnS inclusion encourages the precipitation of Mo-rich primary carbide. The CaO·Al 2 O 3 inclusion cannot act as the nucleation site for the precipitation of the two primary carbides. The solid fraction that the V-rich primary carbide begins to precipitate ranges from 0.965 to 0.983, and that for the Mo-rich primary carbide and the MnS inclusion change from 0.9990 to 0.9998 and from 0.989 to 0.990, respectively.